Apparent Molar Volumes and Expansivities of Ionic Liquids Based on N-Alkyl-N-methylmorpholinium Cations in Acetonitrile - Publikacja - MOST Wiedzy

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Apparent Molar Volumes and Expansivities of Ionic Liquids Based on N-Alkyl-N-methylmorpholinium Cations in Acetonitrile

Abstrakt

Densities of some acetonitrile solutions of ionic liquids based on N-alkyl-N-methyl-morpholinium cations, N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-methyl-N-octylmorpholinium bis(trifluoromethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide were measured at T = (298.15− 318.15) K and at atmospheric pressure. From density data the apparent molar volumes and partial molar volumes of the ILs at infinite dilution as well as the limiting apparent molar expansibilities and the Hepler’s constant values have been evaluated. The results have been discussed in terms of the effect that alkyl chain length of the ILs and experimental temperature have on the ionic liquid−acetonitrile interactions occurring in the studied solutions.

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Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
JOURNAL OF CHEMICAL AND ENGINEERING DATA nr 59, wydanie 3, strony 718 - 725,
ISSN: 0021-9568
Język:
angielski
Rok wydania:
2014
Opis bibliograficzny:
Marcinkowski Ł., Olszewska T., Kloskowski A., Warmińska D.: Apparent Molar Volumes and Expansivities of Ionic Liquids Based on N-Alkyl-N-methylmorpholinium Cations in Acetonitrile// JOURNAL OF CHEMICAL AND ENGINEERING DATA. -Vol. 59, iss. 3 (2014), s.718-725
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1021/je400790d
Weryfikacja:
Politechnika Gdańska

wyświetlono 141 razy

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