Solvation of ionic liquids based on N -methyl- N -alkylmorpholinium cations in N,N -dimethylformamide and N,N -dimethylacetamide – Volumetric and compressibility studies - Publikacja - MOST Wiedzy

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Solvation of ionic liquids based on N -methyl- N -alkylmorpholinium cations in N,N -dimethylformamide and N,N -dimethylacetamide – Volumetric and compressibility studies

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Density and sound velocity of the solutions of ionic liquids based on N-alkyl-N-methyl- morpholinium cations: N-ethyl- -methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-Nmethylmorpholinium bis(trifluoromethanesulfonyl)imide, N-octyl-N-methyl -morpholinium bis(trifluor omethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide in N, N-dimethylformamide and N,N-dimethylacetamide were measured at T = (298.15–318.15) K and at atmospheric pressure. Using experimental data, apparent molar volume and apparent molar compressibility values were calculated and fitted to the Redlich-Meyer type equation which was used to obtain partial molar volume and partial molar isentropic compressibility of the ILs at infinite dilution. By using the density data, the isobaric thermal expansibility coefficients were also estimated. The effect of alkyl chain length of the ILs, experimental temperature and properties of solvent on these thermodynamic properties were discussed.

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Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
JOURNAL OF CHEMICAL THERMODYNAMICS nr 119, strony 92 - 101,
ISSN: 0021-9614
Język:
angielski
Rok wydania:
2018
Opis bibliograficzny:
Marcinkowski Ł., Kloskowski A., Warmińska D.: Solvation of ionic liquids based on N -methyl- N -alkylmorpholinium cations in N,N -dimethylformamide and N,N -dimethylacetamide – Volumetric and compressibility studies// JOURNAL OF CHEMICAL THERMODYNAMICS. -Vol. 119, (2018), s.92-101
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.jct.2017.12.018
Źródła finansowania:
Weryfikacja:
Politechnika Gdańska

wyświetlono 122 razy

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