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Chitin nanowhiskers from shrimp shell waste as green filler in acrylonitrile-butadiene rubber: Processing and performance properties

Abstract

In this work, chitin nanowhiskers with high crystallinity index were obtained from shrimp shells waste using acid hydrolysis method and then comprehensively characterized. Subsequently, the impact of chitin nanowhisker content on processing and performance of acrylonitrile-butadiene rubber based nanocomposites was evaluated. The results showed that the addition of chitin nanowhiskers increased tensile strength and tear strength of nanocomposites by 116% and 54%, which was related to suitable dispersion of chitin nanowhiskers in matrix. Reinforcing effect of chitin nanowhiskers in acrylonitrile-butadiene rubber was also confirmed by Wolff activity coefficient, glass transition temperature and equilibrium swelling measurements. Moreover, it was found that higher content chitin nanowhiskers significantly improve the thermal stability of studied nanocomposites. The incorporation of chitin nanowhiskers resulted in increase of 74 °C for onset degradation temperature. This work confirmed that shrimp shell waste can be upcycled into chitin nanowhiskers - promising green filler in NBR for high-performance elastomeric applications.

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
CARBOHYDRATE POLYMERS no. 245,
ISSN: 0144-8617
Language:
English
Publication year:
2020
Bibliographic description:
Dominic C.d. M., Joseph R., Sabura Begum P., Raghunandanan A., Vackkachan N., Padmanabhan D., Formela K.: Chitin nanowhiskers from shrimp shell waste as green filler in acrylonitrile-butadiene rubber: Processing and performance properties// CARBOHYDRATE POLYMERS -Vol. 245, (2020), s.116505-
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.carbpol.2020.116505
Verified by:
Gdańsk University of Technology

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