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Efficiency of exciton splitting in organic photovoltaic cells within EQE spectrum

Abstract

The paper presents a procedure of estimating the efficiency of exciton splitting at ED/EA interface. The procedure consists in evaluation of splitting of excitons into electron-hole pairs on the basis of the external quantum efficiency spectra of planar cells and spectra of absorbance of active organic layers. The fitting parameters are the exciton splitting probabilities at ED/EA interface. The presented procedure was applied to two different photovoltaic systems: ITO/MoO3/DBP/PTCBI/BCP/Ag and ITO/MoO3/DBP/F16ZnPc/BCP/Ag with quite similar energy diagrams at the ED/EA interface. The analysis performed led us to the conclusion that only the DBP/PTCBI interface can be considered attractive for organic photovoltaics and organic photodetection, while the DBP/F16ZnPc interface does not show any favourable properties for such applications.

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Keywords

Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
APPLIED SURFACE SCIENCE no. 580,
ISSN: 0169-4332
Language:
English
Publication year:
2022
Bibliographic description:
Jarosz G., Signerski R., Marczyński R.: Efficiency of exciton splitting in organic photovoltaic cells within EQE spectrum// APPLIED SURFACE SCIENCE -Vol. 580, (2022), s.152167-
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.apsusc.2021.152167
Sources of funding:
  • COST_FREE
Verified by:
Gdańsk University of Technology

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