Electrodes consisting of PEDOT modified by Prussian Blue analogues deposited onto titania nanotubes – Their highly improved capacitance - Publication - Bridge of Knowledge

Your account

login

Search

Electrodes consisting of PEDOT modified by Prussian Blue analogues deposited onto titania nanotubes – Their highly improved capacitance

Abstract

In this work we present the outstanding energy storage of prepared inorganic-organic heterojunction where hydrogenated ordered titania nanotubes (H-TiO2NT) were modified by the hybrid made of poly(3,4-ethylenedioxythiophene) (pEDOT) and iron hexacyanoferrate centres (Fehcf, Prussian Blue). The material TiO2NT/pEDOT:Fechf was obtained electrochemically by means of: anodization, hydrogenation and finally, electropolymerization of EDOT in the presence of Fe(CN)63 −/4 − ions. Inorganic-organic hybrids were characterized using Raman spectroscopy and secondary ion mass spectrometry (SIMS). The morphology of obtained materials was inspected using scanning electron microscopy (SEM). Electrodes were tested using cyclic voltammetry and galvanostatic charge/discharge cycles in an aqueous electrolyte. The characterization of capacitance was studied by means of multiple (up to 10,000) charge/discharge cycles with the current density of 0.45 mA cm− 2. Electrode materials consisting of H-TiO2, pEDOT and Prussian Blue exhibited the highest capacitance of 26 mF cm− 2 even after 10,000 cycles. Thus, the capacitance of TiO2NT/pEDOT:Fehcf was c.a. 15 and 8 times higher than the capacitance registered for pure and hydrogenated TiO2, respectively.

Citations

  • 2 2

    CrossRef

  • 0

    Web of Science

  • 2 1

    Scopus

Authors (6)

Cite as

Full text

full text is not available in portal

Keywords

Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
SOLID STATE IONICS pages 197 - 201,
ISSN: 0167-2738
Language:
English
Publication year:
2017
Bibliographic description:
Szkoda M., Trzciński K., Rysz J., Gazda M., Siuzdak K., Lisowska-Oleksiak A.: Electrodes consisting of PEDOT modified by Prussian Blue analogues deposited onto titania nanotubes – Their highly improved capacitance// SOLID STATE IONICS. -, nr. 302 (2017), s.197-201
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.ssi.2016.12.025
Verified by:
Gdańsk University of Technology

seen 134 times

Recommended for you

Fabrication and photoactivity of organic-inorganic systems based on titania nanotubes and PEDOT containing redox centres formed by different Prussian Blue analogues

2017

Titania nanotubes modified by a pyrolyzed metal-organic framework with zero valent iron centers as a photoanode with enhanced photoelectrochemical, photocatalytical activity and high capacitance

2018

Widening of the electroactivity potential range by composite formation – capacitive properties of TiO2/BiVO4/PEDOT:PSS electrodes in contact with an aqueous electrolyte

2019

Synthesis and photoelectrochemical behaviour of hydrogenated titania nanotubes modified with conducting polymer infiltrated by redox active network

2016
Meta Tags