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High-temperature properties of titanium-substituted yttrium niobate

Abstract

he defect fluorite titanium-doped yttrium niobate samples Y3Nb1−xTixO7−δ have been synthesized and investigated by the means of high-temperature X-ray diffraction, dilatometry, and thermogravimetry. Thermal expansion coefficients (TECs) as well as chemical expansion coefficients for material with 5, 10, and 15 mol% of titanium were determined. All investigated samples exhibit chemical contraction caused by Ti doping. The values of TECs obtained by two different methods show similar results, which suggests the isotropy of the polycrystalline ceramic. Thermogravimetric studies have shown that all of the compositions exhibit a mass increase upon being exposed to a humid air atmosphere. The total proton concentration calculated on the basis of these results was in the range of 0.1 mol%. Moreover, titanium content influences chemical expansion coefficient, water uptake, and protonic defects concentration, whereas it does not significantly affect the values of TECs

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
JOURNAL OF MATERIALS RESEARCH no. 34, pages 3312 - 3318,
ISSN: 0884-2914
Language:
English
Publication year:
2019
Bibliographic description:
Mielewczyk-Gryń A., Winiarz P., Wachowski S., Gazda M.: High-temperature properties of titanium-substituted yttrium niobate// JOURNAL OF MATERIALS RESEARCH -Vol. 34,iss. 19 (2019), s.3312-3318
DOI:
Digital Object Identifier (open in new tab) 10.1557/jmr.2019.187
Verified by:
Gdańsk University of Technology

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