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Removal efficiency of phenol by ozonation process with calcium peroxide from aqueous solutions

Abstract

Phenol has been introduced as a priority pollutant by the US Environmental Protection Agency. Advanced oxidation processes (AOPs) are one of the most efcient methods for removal of non-degradable organic pollutants in aqueous solutions. The removal efciencies of phenol and COD under optimal conditions pH=3, phenol concentration=5 mg/L, CaO2 concentration=0.025 mg/L, temperature 25 °C, 1 g/min ozonation rate and contact time=90 min in synthetic and real samples (Zarand coal washing factory in Kerman) were obtained 97.8%, 87% and 80%, 65.4%, respectively. The kinetics of phenol decomposition follows from the pseudo-frst-order equation. Thermodynamic studies show that phenol decomposition with ozonation and calcium peroxide is an endothermic process. The use of ozonation process with calcium peroxide is an efcient method and can be recommended as a coefcient method for the removal of phenol.

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Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
Applied Water Science no. 11, pages 1 - 9,
ISSN: 2190-5487
Language:
English
Publication year:
2021
Bibliographic description:
Honarmandrad Z., Javid N., Malakootian M.: Removal efficiency of phenol by ozonation process with calcium peroxide from aqueous solutions// Applied Water Science -Vol. 11,iss. 2 (2021), s.1-9
DOI:
Digital Object Identifier (open in new tab) 10.1007/s13201-020-01344-7
Verified by:
Gdańsk University of Technology

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