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Synthesis, characterization and application of cross-linked functional terpolymer through epoxy group as sorbent for extraction of cadmium from waters and foods: Multivariate optimization
Abstract
The purpose of this study was to develop a selective sorbent for cadmium ions (Cd(II)) enrichment in orbital shaker assisted solid phase microextraction (OS-SPME) from different aqueous and food samples. A maleic anhydride-styrene-glycidyl methacrylate (MA-St-GMA) terpolymer was synthesized and characterized in detail. Experimental variables of sample preparation step were optimized using a central composite design (CCD). The final determination step was performed using flame atomic absorption spectroscopy (FAAS). The MA-St-GMA sorbent exhibited a high adsorption capacity (195.9 mg g−1) for the Cd(II) ion. The developed method under optimal conditions provides satisfactory performance and a significant improvement compared to other protocols available in the literature. The linear range and detection limit of the method is 0.1–130 ng mL−1 and 0.03 ng mL−1, respectively. The robustness, intraday/interday precision, selectivity, and accuracy of the method were investigated. To further validate the method, a dedicated series of analysis was performed using certified reference materials (CRMs). This part of the study confirmed the applicability of the method for routine analysis. The OS-SPME-FAAS method was validated using water and food samples. Relative standard deviations and recovery for real-world samples were in ranges 1.7–2.2 % and 95.5–98.5 %, respectively. As a result, the MA-St-GMA sorbent showed that it could quantitatively extract Cd(II) ions from aqueous solution.
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Authors (5)
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Ersen Yılmaz
- Munzur University, Dept. Machinery Programme, Tunceli, Türkiye
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Ali Boztuğ
- Sivas Cumhuriyet University, Faculty of Science, Department of Chemistry, Sivas, Türkiye
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Nail Altunay
- Sivas Cumhuriyet University, Faculty of Science, Department of Chemistry, Sivas, Türkiye
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Full text
- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.foodchem.2023.137590
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Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
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FOOD CHEMISTRY
no. 435,
ISSN: 0308-8146 - Language:
- English
- Publication year:
- 2024
- Bibliographic description:
- Yılmaz E., Boztuğ A., Haq H., Boczkaj G., Altunay N.: Synthesis, characterization and application of cross-linked functional terpolymer through epoxy group as sorbent for extraction of cadmium from waters and foods: Multivariate optimization// FOOD CHEMISTRY -Vol. 435, (2024), s.137590-
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.foodchem.2023.137590
- Sources of funding:
-
- Free publication
- Verified by:
- Gdańsk University of Technology
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