The reactions of dialkyl phosphites and phosphine oxides with iodosylbenzene

Sławomir Makowiec; Janusz Rachoń

doi:10.1080/10426500210674

The reactions of dialkyl phosphites and phosphine oxides with iodosylbenzene

Abstract

The reaction of iodosylbenzene with >P(O)H type of acids (dialkyl phosphites, secondary phosphine oxides) was studied. The acids of >P(O)H type add to iodosylbenzene to yield intermediate 6 which in the aprotic solvents yields oxidation products, it means >P(O)OH acids and/or anhydride of >P(O)OP(O)< type. On the other hand if the reaction is performed in alcohol as a solvent in the presence of sodium alcoholate >P(O)OR ester is the major product.

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Authors (2)

Sławomir Makowiec dr hab.
Janusz Rachoń prof. dr hab. inż.

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Category:: Articles
Type:: artykuł w czasopiśmie z listy filadelfijskiej
Published in:: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS no. 177, edition 4, pages 941 - 955,
ISSN: 1042-6507
Language:: English
Publication year:: 2002
Bibliographic description:: Makowiec S., Rachoń J.: The reactions of dialkyl phosphites and phosphine oxides with iodosylbenzene// PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. -Vol. 177., iss. 4 (2002), s.941-955
DOI:: Digital Object Identifier (open in new tab) 10.1080/10426500210674
Verified by:: Gdańsk University of Technology