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The stereostructure of candicidin D.

Abstract

The candicidin D stereostructure was established based on NMR studies including DQF-COSY, ROESY, HSQC and HMBC experiments. The relative configurations of the candicidin D stereogenic centers were assigned as the following: 9R*, 11S*, 13S*, 15R*, 17S*, 18R*, 19S*, 21R*, 36S*, 37R*, 38S*, 40S* and 41S*. The geometry of the heptaene chromophore was defined as 22E, 24E, 26Z, 28Z, 30E, 32E and 34E.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
JOURNAL OF ANTIBIOTICS no. 68, edition 8, pages 504 - 510,
ISSN: 0021-8820
Language:
English
Publication year:
2015
Bibliographic description:
Szwarc K., Szczeblewski P., Sowiński P., Borowski E., Pawlak J.: The stereostructure of candicidin D.// JOURNAL OF ANTIBIOTICS. -Vol. 68, iss. 8 (2015), s.504-510
DOI:
Digital Object Identifier (open in new tab) 10.1038/ja.2015.17
Verified by:
Gdańsk University of Technology

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