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Abstract
The new silicon–sulfur compound: disiloxane-1,3-dithiol was obtained from silicon disulfide and 2,6-diisopropylphenol in a reaction catalyzed by imidazole or 4-(dimethylamino)pyridine (DMAP). Crystal structure of disiloxane–1,3-dithiol reveals a close-to-linear Si–O–Si angle and a mutual trans position of the two hydrosulfido groups. The compound forms a chelating mononuclear complex with cadmium ions.
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Authors (7)
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Eleonora Conterosito dr
- Dipartimento di Scienze e Innovazione Tecnologica and CrisDi Interdepartmental Center for Crystallography, Università del Piemonte Orientale Dipartimento di Scienze e Innovazione Tecnologica and CrisDi Interdepartmental Center for Crystallography
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Marco Milanesio prof.
- Dipartimento di Scienze e Innovazione Tecnologica and CrisDi Interdepartmental Center for Crystallography, Università del Piemonte Orientale Dipartimento di Scienze e Innovazione Tecnologica and CrisDi Dipartimento di Scienze e Innovazione Tecnologica and CrisDi Interdepartmental Center for Crystallography
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Katarzyna Rzymowska mgr inż.
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Krzysztof Brzozowski dr
- Wydział Chemii Uniwersytetu Gdańskiego Zespół Pracowni Fizyko-Chemicznych
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Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
no. 2015,
edition 19,
pages 3059 - 3065,
ISSN: 1434-1948 - Language:
- English
- Publication year:
- 2015
- Bibliographic description:
- Ciborska A., Conterosito E., Milanesio M., Kazimierczuk K., Rzymowska K., Brzozowski K., Dołęga A.: The Syntheses and Crystal Structures of the First Disiloxane-1,3-dithiol and Its Cadmium Complex.// EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. -Vol. 2015, iss. 19 (2015), s.3059-3065
- DOI:
- Digital Object Identifier (open in new tab) 10.1002/ejic.201500457
- Verified by:
- Gdańsk University of Technology
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