Wyszukiwarka
Evaluation of structural change during fast transformation process of cross-linked NR into liquid NR by light pyrolysis
Abstrakt
The presence of cross-linked networks in rubber creates a tremendous problem for recycling and reusing of waste rubber. Fast transformation of cross-linked natural rubber (NR) into liquid natural rubber was carried out by light pyrolysis in temperature range from 240 to 300 °C in variable time (in range: 1–30 min). The transformation efficiency was evaluated by measuring the sol fraction and the cross-link density of the gel fraction. Over 80 wt% sol fraction was obtained at 280 °C in 15 min and 100 wt% sol fraction was obtained at 300 °C in 3 min. The chemical structure of sol fraction was characterized by gel permeation chromatography, nuclear magnetic resonance and infrared spectroscopy. The molecular weight of sol fraction in cross-linked NR processed at 280 °C and 300 °C decreased when gel fraction is over 50%. The nuclear magnetic resonance results showed that mono-sulfidic linkages occurred mainly in the sol fraction of liquid NR obtained at 300 °C. Isomerization from cis to trans form of isoprene unit in NR increased with extending pyrolysis time.
Cytowania
-
3 0
CrossRef
-
0
Web of Science
-
3 0
Scopus
Autorzy (4)
-
Xiaoyu Wu
- Shanghai Jiao Tong University Department of Polymer Science and Engineering
-
Raqiqa Rasool
- Shanghai Jiao Tong University Department of Polymer Science and Engineering
-
Shifeng Wang
- Shanghai Jiao Tong University Department of Polymer Science and Engineering
Cytuj jako
Pełna treść
pełna treść publikacji nie jest dostępna w portalu
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuł w czasopiśmie wyróżnionym w JCR
- Opublikowano w:
-
POLYMER DEGRADATION AND STABILITY
nr 136,
strony 48 - 57,
ISSN: 0141-3910 - Język:
- angielski
- Rok wydania:
- 2017
- Opis bibliograficzny:
- Wu X., Formela K., Rasool R., Wang S.: Evaluation of structural change during fast transformation process of cross-linked NR into liquid NR by light pyrolysis// POLYMER DEGRADATION AND STABILITY. -Vol. 136, (2017), s.48-57
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.polymdegradstab.2016.12.009
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 113 razy
Publikacje, które mogą cię zainteresować
Thermo-oxidative exfoliation of carbon black from ground tire rubber as potential reinforcement in green tires
- A. Hassan,
- Z. Zhang,
- K. Formela
- + 1 autorów
Vegetable derived-oil facilitating carbon black migration from waste tire rubbers and its reinforcement effect
- P. Song,
- C. Wan,
- Y. Xie
- + 2 autorów
Ground tire rubber thermo-mechanically devulcanized in the presence of waste engine oil as asphalt modifier
- Y. Li,
- A. Shen,
- Z. Lyu
- + 3 autorów