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Year 2025
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Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B–O–C, B–O–B, and B–O–P structural motifs
PublicationThe reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the Lewis acidic boron center and the Lewis basic phosphido ligand connected by a covalent bond. The reaction of the title cation with CO2 led to the insertion of a CO2 molecule into the P–B...
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Active learning on stacked machine learning techniques for predicting compressive strength of alkali-activated ultra-high-performance concrete
PublicationConventional ultra-high performance concrete (UHPC) has excellent development potential. However, a significant quantity of CO2 is produced throughout the cement-making process, which is in contrary to the current worldwide trend of lowering emissions and conserving energy, thus restricting the further advancement of UHPC. Considering climate change and sustainability concerns, cementless, eco-friendly, alkali-activated UHPC (AA-UHPC)...
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Anterior prefrontal EEG theta activities indicate memory and executive functions in epilepsy patients
PublicationObjective: Cognitive deficits are one of the most debilitating comorbidities in epilepsy and other neurodegenerative, neuropsychiatric, and neurodevelopmental brain disorders. Current diagnostic and therapeutic options are limited and lack objective measures of the underlying neural activities. In this study, electrophysiological biomarkers that reflect cognitive functions in clinically validated batteries were determined to aid...
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Automatic Cleaning of Time Series Data in Rural Internet of Things Ecosystems That Use Nomadic Gateways
PublicationA serious limitation to the deployment of IoT solutions in rural areas may be the lack of available telecommunications infrastructure enabling the continuous collection of measurement data. A nomadic computing system, using a UAV carrying an on-board gateway, can handle this; it leads, however, to a number of technical challenges. One is the intermittent collection of data from ground sensors governed by weather conditions for...
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BEZPIECZEŃSTWO DZIECI W CYBERPRZESTRZENI KLUCZOWE ZAGADNIENIA I PRZEPISY PRAWNE
PublicationBezpieczeństwo dzieci w cyberprzestrzeni kluczowe zagadnienia i przepisy prawneOpracowanie eksperckie Marcin Niedopytalski W dobie powszechnej cyfryzacji, kiedy dostęp do internetu stał się nieodłącznym elementem życia codziennego, kwestia bezpieczeństwa dzieci w sieci nabiera szczególnego znaczenia. Z jednej strony obserwujemy korzyści płynące z edukacji online, swobodnego dostępu do informacji...
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Born Twice: The Role of Social Media in Identity Redefinition after Sudden Disability
PublicationFrom being attacked by a shark to being stricken by illness, people who acquire disabilities later in life have unique lived experiences. There is, however, a commonality that binds them: the loss of a former identity and a rebirth into another life. They may also struggle with self-acceptance as they shun societal stigmas and perceived deviance from cultural norms. Through a netnographic study, we examine how identities are redefined...
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Calculations of Cross-Sections for Positron Scattering on Benzene
PublicationIn this work, we present a theoretical study on positron scattering by benzene molecules over a broad energy range (1–1000 eV). The aim of this work is to provide missing data from partial cross-sections for specific processes. In particular, calculations of cross-sections for direct ionization and electronic excitation were carried out for benzene molecules in the gas phase. An estimate for the cross-section for positronium formation...
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Chemical insight into pros and cons of coffees from different regions
PublicationThe main aim of this work was to study the chemical composition of eighteen ground coffees from different countries and continents with regard to the content of hazardous substances as radioactive elements (40K, 226Ra, 228Ra, 234U, 238U and 137Cs), metals, including heavy metals, aluminum and some microelements (V, Cr, Mn, Fe, Co, Ni, Cu, Zn) as well as substances that have a positive effect on human health and well-being (polyphenols,...
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Company culture matters! Knowledge-driven companies' way to innovations and sustainability
PublicationCompanies today aim to adapt to rapidly changing business environments by acquiring knowledge, developing dynamic capabilities, fostering market innovations, and ensuring sustainability. Achieving these goals requires a supportive company culture aligned with its structure and strategy. This study proves the critical role of company culture in sustainability based on a sample of 496 Polish knowledge workers, using structural equation...
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Declarative ship arenas under favourable conditions
PublicationAccording to maritime regulations, a collision-avoidance action shall be taken at an “ample time” while strict interpretation of this term is ambiguous. Evasive manoeuvres, executed by marine navigators on a daily basis, are usually carried out well in advance, while the distance at which they decide to perform such a manoeuvre is mostly subjective and results, e.g., from the navigator's seagoing experience. A proper understanding...
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Deep eutectic solvent enhances antibacterial activity of a modular lytic enzyme against Acinetobacter baumannii
PublicationIn this study, we evaluated the combined effect between MLE-15, a modular lytic enzyme composed of four building blocks, and reline, a natural deep eutectic solvent. The bioinformatic analysis allowed us to determine the spatial architecture of MLE-15, whose components were bactericidal peptide cecropin A connected via a flexible linker to the cell wall binding domain (CBD) of mesophilic 201ϕ2 − 1 endolysin and catalytic domain...
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Effects of aggregate crushing and strain rate on fracture in compressive concrete with a DEM-based breakage model
PublicationW tym artykule zbadano, w jaki sposób kruche kruszywa wpływają na mezoskopowe zachowanie dynamiczne betonu w warunkach jednoosiowego ściskania. Przeprowadzono obszerne dynamiczne obliczenia dwuwymiarowe (2D), aby zbadać wpływ kruszenia kruszywa i szybkości odkształcania na dynamiczną wytrzymałość betonu i wzory pęknięć. Wykorzystując model pękania oparty na DEM, beton symulowano jako materiał czterofazowy składający się z kruszywa,...
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Efficacy of modal curvature damage detection in various pre-damage data assumptions and modal identification techniques
PublicationThe efficacy of modal curvature approach for damage localization is discussed in the paper in the context of input data. Three modal identification methods, i.e., Eigensystem Realization Algorithm (ERA), Natural Excitation Technique with ERA (NExT-ERA) and Covariance Driven Stochastic Subspace Identification (SSI-Cov), and four methods of determining baseline data, i.e., real measurement of the undamaged state, analytical function,...
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Enhanced sorption of inhibitory compounds from fermentation broth using a MOF@pseudo-DES composite
PublicationThe increase in biorefinery processes underscores the need for effective biofuel generation; nevertheless, inhibitors such as hydroquinone (HQ), 5-hydroxymethylfurfural (HMF), furfural (FF), and vanillin (VAN) resulting from biomass degradation impede microbial growth and process efficiency. Herein, a deep eutectic solvent (DES)-like substance was in-situ generated on the surface of NH2-UiO-66 via a post-synthetic coating process...
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Exploration of Behavioral Patterns and Cognitive Biases among Stock Market Investors
PublicationThis study aims to explore behavioral patterns and cognitive biases among stock market investors. By analyzing investor behavior through a stock market simulator, the research seeks to understand the impact of cognitive biases on investment decisions. The methodology encompasses a detailed analysis of transaction data to identify prevalent patterns and biases. Findings suggest that biases such as overconfidence, representativeness...
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Fatigue Damage Evolution in SS316L Produced by Powder Bed Fusion in Different Orientations with Reused Powder Feedstock
PublicationBackground Metal Laser Powder Bed Fusion Melting (LPBF-M) is considered economically viable and environmentally sustainable because of the possibility of reusing the residual powder feedstock leftover in the build chamber after a part build is completed. There is however limited information on the fatigue damage development of LPBF-M samples made from reused feedstock. Objective In this paper, the stainless steel 316 L (SS316L)...
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Finite Element Analysis of Occupant Risk in Vehicular Impacts into Cluster Mailboxes
PublicationThe deployment of cluster mailboxes (CMs) in the U.S. has raised safety concerns for passengers in potential vehicular crashes involving CMs. This study investigated the crashworthiness of two types of CMs through nonlinear finite element simulations. Two configurations of CM arrangements were considered: a single- and a dual-unit setup. These CM designs were tested on flat-road conditions with and without a curb. A 2010 Toyota...
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Implementing an Analytical Model to Elucidate the Impacts of Nanostructure Size and Topology of Morphologically Diverse Zinc Oxide on Gas Sensing
PublicationThe development of state-of-the-art gas sensors based on metal oxide semiconductors (MOS) to monitor hazardous and greenhouse gas (e.g., methane, CH4, and carbon dioxide, CO2) has been significantly advanced. Moreover, the morphological and topographical structures of MOSs have significantly influenced the gas sensors by means of surface catalytic activities. This work examines the impact of morphological and topological networked...
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Is DAO Governance Fostering Democracy? Reviewing Decision-Making in Decentraland
PublicationThis study analyzes voting dynamics and proposal outcomes within Decentraland, a prominent Decentralized Autonomous Organization (DAO), by examining its voting behaviors and decision outcomes. We offer insights into how a DAO is employed to facilitate decision-making and discern the nature of the issues about which decisions are made. DAOs promise horizontal and democratic decision-making. However, our research reveals...
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Joint foreign ownership and global value chains effects on productivity: a comparison of firms from Poland and Germany
PublicationPurpose The study aims to examine the joint effects of foreign ownership (FO) and involvement in global value chains (GVCs) on the productivity performance of firms from a catching-up country (Poland) and a leader economy (Germany). Design/methodology/approach The authors use micro-level data on firms combined with several sector-level GVC participation measures. The authors investigate whether the link between productivity and...
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KLUCZOWA ROLA KWALIFIKOWANEGO PRACOWNIKA OCHRONY W BUDOWANIU BEZPIECZEŃSTWA PUBLICZNEGO
PublicationWspółczesne wyzwania w zakresie ochrony osób i mienia sprawiają, że grupy interwencyjne odgrywają coraz ważniejszą rolę w systemie bezpieczeństwa. Ich zadania, wymagające zarówno wiedzy teoretycznej, jak i doskonałej sprawności fizycznej oraz umiejętności reagowania w sytuacjach kryzysowych, czynią ten zawód nie tylko odpowiedzialnym, ale i niezbędnym w dzisiejszym świecie. Grupy interwencyjne stanowią mobilne...
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MXene-based materials as adsorbents, photocatalysts, membranes and sensors for detection and removal of emerging and gaseous pollutants: A comprehensive review
Publication2D materials have garnered significant attention as potential solutions to various environmental challenges. Graphene, molybdenum disulfide, MXenes, and boron nitride have emerged as the most popular candidates among these materials. This article presents a comprehensive review and discussion on the emerging applications of MXenes in environmental engineering. MXenes have demonstrated immense potential as future materials for adsorption...
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New insights into structural, optical, electrical and thermoelectric behavior of Na0.5Bi0.5TiO3 single crystals
PublicationThe single crystals of lead-free Na0.5Bi0.5TiO3 were grown using the Czochralski method. The energy gaps determined from X-ray photoelectron spectroscopy (XPS) and optical measurements were approximately 2.92 eV. The current-voltage characteristics, depolarization current, dc (σdc) and ac (σac) electrical conductivity, and Seebeck coefficient of the crystals were investigated. The frequency/temperature-dependent electrical properties...
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Numerical Simulation of Light to Heat Conversion by Plasmonic Nanoheaters
PublicationPlasmonic nanoparticles are widely recognized as photothermal conversion agents, i.e., nanotransducers or nanoheaters. Translation of these materials into practical applications requires quantitative analyses of their photothermal conversion efficiencies (η). However, the value of η obtained for different materials is dramatically influenced by the experimental setup and method of calculation. Here, we evaluate the most common...
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On a fully three-dimensional bending analysis of very thick smart composite cube-like bulk structures
PublicationHere we discuss the behaviour of very thick composite plates considering electro-magneto-elastic coupling of various types using fully three-dimensional (3D) kinematics. Published research highlights a lack of studies on the 3D mechanics of smart composite plates that integrate both higher-order (flexoelectric/flexomagnetic) and lower-order (piezoelectric/piezomagnetic) multiple physical fields (electro-magneto-elastic). The common...
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On nonlinear 3D electro-elastic numerical modeling of two-phase inhomogeneous FG piezocomposites reinforced with GNPs
PublicationThe novelty here comes from not only the perfect nonlinear three-dimensional (3D) electro-elasticity investigation but also the mixed material itself. The literature widely showed mechanical assessments on the piezoelectric structures; however, a lack of nonlinear three-dimensional elasticity studies has been witnessed on these kinds of smart materials. Therefore, a nonlinear 3D elasticity-piezoelectricity coupling is considered...
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Opposite effect of the Cu photodeposition on the ∙OH generation and diclofenac degradation depends on the exposed anatase facet
PublicationExposition of a specific crystal facets and modification with co-catalysts are often used in order to improve photocatalytic activity of a material. However, considering complexity of these interactions, it is still challenging to fully understand and predict activity of a specific system. Here, we report combination of the {0 0 1} and {1 0 1} crystal facets of anatase TiO2 with CuXO co-catalyst, applied for diclofenac degradation,...
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Pomoc psychologiczno-pedagogiczna Dz.U.2023 po. 1798 opracowanie Marcin Niedopytalski
PublicationPomoc psychologiczno-pedagogiczna w świetle Rozporządzenia Dz.U. 2023 poz. 1798 – analiza i perspektywyAutor: Marcin Niedopytalski Pomoc psychologiczno-pedagogiczna jest jednym z kluczowych elementów wspierania uczniów w polskim systemie edukacji. Rozporządzenie Ministra Edukacji Narodowej z dnia 9 sierpnia 2017 r., w brzmieniu ustalonym jednolitym tekstem opublikowanym w Dzienniku...
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Predicting a passenger ship's response during evasive maneuvers using Bayesian Learning
PublicationThe rapidly advancing automation of the maritime industry – for instance, through onboard Decision Support Systems (DSS) – can facilitate the introduction of advanced solutions supporting the process of collision avoidance at sea. Nevertheless, relevant solutions that aim to correctly predict a ship's behavior in irregular waves are only available to a limited extent by omitting the impact of wave stochastics on resulting evasive...
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Quality Evaluation of Small Features Fabricated by Fused Filament Fabrication Method
PublicationThe purpose of this research was to evaluate the quality of small features fabricated by the fused filament fabrication (FFF) method. The samples containing circular and square cross-sections through holes with different dimensions, lengths, and orientation angles were printed from ABS (acrylonitrile butadiene styrene) filament. The adopted optical inspection method allowed us to conduct observations of individual features and...
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Restrained differential of a graph
PublicationGiven a graph $G=(V(G), E(G))$ and a vertex $v\in V(G)$, the {open neighbourhood} of $v$ is defined to be $N(v)=\{u\in V(G) :\, uv\in E(G)\}$. The {external neighbourhood} of a set $S\subseteq V(G)$ is defined as $S_e=\left(\cup_{v\in S}N(v)\right)\setminus S$, while the \emph{restrained external neighbourhood} of $S$ is defined as $S_r=\{v\in S_e : N(v)\cap S_e\neq \varnothing\}$. The restrained differential of a graph $G$ is...
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Rozporządzenia Ministra Edukacji Narodowej i Sportu z 31 grudnia 2002 r. w sprawie bezpieczeństwa i higieny w szkołach
PublicationBezpieczeństwo i higiena w środowisku szkolnym to jeden z kluczowych filarów funkcjonowania całego...
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Self-Calibrating Stress Measurement System Based on Multidirectional Barkhausen Noise Measurements
PublicationThe system presented in this paper enables automatization of the two-dimensional calibration process (determination of Barkhausen noise (BN) intensity dependence on in-plane components of strain). Then, using dedicated software created by the authors in LabVIEW environment, and with the help of two dimensional calibration data one can effectively determine strain and stress distribution i.e. magnitude and orientation of main strain/stress...
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Solvent Selection as a Key Factor in the Performance of Semitransparent Heterojunctions Composed of Hydrogenated Nanotubes and Bismuth Sulfides
PublicationResearch on titanium nanotubes modified with metal sulfides, particularly bismuth sulfide (Bi2S3), aims to create heterostructures that efficiently absorb sunlight and then separate photogenerated charge carriers, thereby enhancing the energy conversion efficiency. This study shows a key role of solvent used for sulfide and bismuth salt solutions used during successive ionic layer adsorption and reaction (SILAR) onto the morphology,...
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Sustainability, reliability, and durability of civil engineering structures
PublicationConsidering the Bulletin Readers’ interest in civil engineering,the Special Section “Sustainability, reliability, and durability of civil engineering structures” is now presented, with papers that, by studying specific cases, fully embrace all aspects related to the topic, starting from geometry design, determination of load acting on a structure, characteristics of the material for construction purpose, characteristics of structural...
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Technological Considerations of Periodic Repair Works of Concrete Industrial Floors
PublicationConcrete floors are among the elements in construction facilities whose design requires engineering experience, workmanship requires the maintenance of a technological regime, while during their operation it is necessary to conduct periodic repairs. Concrete floors are most often used as working and communication space in industrial facilities, and very often they are also a functional element in objects that are immovable monuments....
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Theoretical design of nanocatalysts based on (Fe2O3)n clusters for hydrogen production from ammonia
PublicationThe catalytic activities of high-spin small Fe(III) oxides have been investigated for efficient hydrogen production through ammonia decomposition, using the artificial force induced reaction method within the framework of density functional theory with the B3LYP hybrid exchange–correlation functional. Our results reveal that the adsorption free energy of NH3 on (Fe2O3 )n (n = 1–4) decreases with increasing cluster size up to n...
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Thermoelectric and electrical properties of triple-conducting multicomponent oxides based on substituted barium cerate-zirconate
PublicationMulticomponent oxides often have exceptional thermal stability and interesting electronic properties. The present work presents the thermoelectric and electrical properties of the Ba(Zr0.2Hf0.2Sn0.2Ti0.2Fe0.2)O3−δ and Ba(Zr0.1Hf0.1Sn0.1Ti0.1Co0.1Ce0.1Bi0.1Fe0.1Y0.1Zn0.1)O3−δ multicomponent perovskites. Single-phase cubic perovskites were synthesized using the solid-state reaction method. They were characterized using X-ray...
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Transformacja firm ochroniarskich i nowoczesne technologie w ochronie
PublicationTransformacja sektora ochrony w nadchodzących latach wymaga głębokiego zrozumienia wyzwań współczesności, innowacji technologicznych oraz skutecznego zarządzania zasobami ludzkimi. Wprowadzenie nowych rozwiązań, takich jak sztuczna inteligencja, obsługa dronów, czy systemy wspomagające strzelectwo, stanowi fundament nowoczesnej ochrony osób i mienia. Jako ekspert w tej dziedzinie, chciałbym przedstawić kompleksowy plan...
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Turystyka Szkolna Bezpieczeństwo i Rozwój MEN Z DNIA 25 MAJA 2018
PublicationRozporządzenie Ministra Edukacji Narodowej z dnia 25 maja 2018 r w sprawie warunków i sposobu organizowania przez publiczne przedszkola szkoły i placówki krajoznawstwa i turystyki jest niezwykle istotnym aktem prawnym który reguluje zasady bezpiecznego i efektywnego planowania różnorodnych form wypoczynku wycieczek krajoznawczych oraz innych przedsięwzięć turystycznych realizowanych w ramach zadań statutowych tych jednostek...
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Ultra-Compact Quintuple-Band Terahertz Metamaterial Biosensor for Enhanced Blood Cancer Diagnostics
PublicationCancer and its diverse variations pose one of the most significant threats to human health and well-being. One of the most aggressive forms is blood cancer, originating from bone marrow cells and disrupting the production of normal blood cells. The incidence of blood cancer is steadily increasing, driven by both genetic and environmental factors. Therefore, early detection is crucial as it enhances treatment outcomes and improves...
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UV light-activated gas mixture sensing by ink-printed WS2 layer
PublicationWe fabricated a sensing layer from ink-printed WS2 flakes and utilized it for UV-activated gas sensing. The optical imaging of the structure made by repeated printing revealed the continuous layer comprising sub-µm flakes, confirmed independently by small-area AFM images (1×1 µm2). The activity of the sensing surface was investigated locally via AFM scanning of the surface with a polarized probing tip. The results indicated that...
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View Quality Assessments: A Pilot Study of Field Methods
PublicationThis paper describes findings from a workshop during which participants evaluated a series of windowviews. An explorative approach was applied to identify issues and testing methods useful in daylightresearch. The participants visited nine rooms with views of varied content, complexity, and viewingdistance under the overcast sky. Participants used surveys with quantitative and qualitative questions,hand drawings, illuminance measurements,...
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Vitamin B9 as a new eco-friendly corrosion inhibitor for copper in 3.5% NaCl solution
PublicationFolic acid salt (sodium folate) was studied as an eco-friendly and non-toxic copper corrosion inhibitor in 3.5% NaCl solution. Electrochemical impedance spectroscopy, polarization resistance and weight-loss measurements show that the inhibitor efficiency increases with concentration (the highest value- approx. 96% was reported for the solution containing 16 mM sodium folate after 24 h). EIS data and Tafel plots indicate that sodium...
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WSPÓŁCZESNE ZAGROŻENIA CYBERNETYCZNE METODY OSZUSTW I SKUTECZNE STRATEGIE OCHRONY
PublicationW dobie globalnej cyfryzacji i rosnącej roli technologii telekomunikacyjnych coraz więcej osób pada ofiarą oszustw związanych z fałszywymi połączeniami telefonicznymi, wiadomościami SMS oraz oszustwami internetowymi. Przestępcy posługują się zaawansowanymi metodami socjotechnicznymi, a wraz z rozwojem sztucznej inteligencji (AI) ich techniki stają się coraz bardziej wyrafinowane i trudniejsze do wykrycia. Niniejszy artykuł przedstawia...
Year 2024
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3-D Printable Metal-Dielectric Metasurface for Risley Prism-Based Beam-Steering Antennas
PublicationA 3-D printable, planar, metal-dielectric metasurface-based, 2-D beam-steering system for aperture-type antennas is presented in this paper. This beam steering system, also known as the near-field meta-steering system, comprises two fully passive phase-gradient metasurfaces placed in the antenna’s nearfield region to steer the radiation beam. To address the non-uniform electric field phase of the aperture antenna, phase correction...
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9,10-Dioxoanthracenyldithiocarbamates effectively inhibit the proliferation of non-small cell lung cancer by targeting multiple protein tyrosine kinases
PublicationAnthraquinones have attracted considerable interest in the realm of cancer treatment owing to their potent anticancer properties. This study evaluates the potential of a series of new anthraquinone derivatives as anticancer agents for non-small-cell lung cancer (NSCLC). The compounds were subjected to a range of tests to assess their cytotoxic and apoptotic properties, ability to inhibit colony formation, pro-DNA damage functions,...
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A 0.5 V Nanowatt Biquadratic Low-Pass Filter with Tunable Quality Factor for Electronic Cochlea Applications
PublicationA novel implementation of an analogue low-power, second-order, low-pass filter with tunable quality factor (Q) is presented and discussed. The filter feature is a relatively simple, buffer-based, circuit network consisting of eleven transistors operating in a subthreshold region. Q tuning is accomplished by injecting direct current into a network node, which changes the output resistance of the transistors and, as a result, modifies...
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A Closed Bipolar Electrochemical Cell for the Interrogation of BDD Single Particles: Electrochemical Advanced Oxidation
PublicationA closed bipolar electrochemical cell containing two conductive boron-doped diamond (BDD) particles of size 250 – 350 m, produced by high-pressure high-temperature (HPHT) synthesis, has been used to demonstrate the applicability of single BDD particles for electrochemical oxidative degradation of the dye, methylene blue (MB). The cell is fabricated using stereolithography 3D printing and the BDD particles are located at either...
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A closer look at how the dispersive liquid–liquid microextraction method works. Investigation of the effect of solvent mixture composition on the quality and stability of the cloudy state
PublicationThe dispersive liquid–liquid microextraction (DLLME) is one of the most popular miniaturized extraction procedures. In this paper, the degree of dispersion and dispersion stability were studied with the aim to assess the correlations of these parameters with efficiency for the selected analytical application. The dependence between the degree of dispersion (cloudy state quality) and its stability obtained by various emulsification...