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Synthesis and crystal structure of ferrocenyl benzothiazole derivatives

Abstract

Novel ferrocenyl-containing benzothiazole derivatives were synthesised in moderate yields by one-pot α-amidoalkylation of ferrocene. The reaction conditions were critically evaluated and the crystal structure of one of the amidoalkylated ferrocenes was resolved. Oxidation of the obtained compounds led to known fully aromatic 2-ferrocenylbenzothiazole in 81 % yield, which represents a convenient alternative to earlier methods utilizing cyclocondensation reactions.

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
JOURNAL OF ORGANOMETALLIC CHEMISTRY no. 1001,
ISSN: 0022-328X
Language:
English
Publication year:
2023
Bibliographic description:
Stremski Y., Bachvarova M., Statkova-Abeghe S., Angelov P., Ivanov I., Ahmedova A., Dołęga A.: Synthesis and crystal structure of ferrocenyl benzothiazole derivatives// JOURNAL OF ORGANOMETALLIC CHEMISTRY -Vol. 1001, (2023), s.122871-
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.jorganchem.2023.122871
Sources of funding:
  • Statutory activity/subsidy
Verified by:
Gdańsk University of Technology

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