Katarzyna Klimsiak - Publications - Bridge of Knowledge

inż. Katarzyna Klimsiak

Employment

No data

Keywords Help

Publications

results on page:
year:
- selected sort by year newest first
- sort by year oldest first
title:
- selected sort by title A-Z
- sort by title Z-A
citation:
- sort by citation descending
- sort by citation ascending

Filters

total: 1

Year 2022

Phosphinoborinium cation: a synthon for cationic B-P bond systems
Publication
- CHEMICAL COMMUNICATIONS - Year 2022
Herein, we report access to phosphinoborinium cations via heterolytic cleavage of the boron-bromide bond in bromophosphinoborane. The product of the reaction was isolated as a dimeric dication possessing a planar P2B2 core. Activation of C-H and C-P bonds in the dication led to formation of the borinium-phosphaborene adduct. Reactivity studies revealed that title cation exhibits ambiphilic properties and intramolecular frustrated...

Full text available to download

seen 552 times