Katarzyna Klimsiak - Publications - Bridge of Knowledge

inż. Katarzyna Klimsiak

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Year 2022

Phosphinoborinium cation: a synthon for cationic B-P bond systems
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- CHEMICAL COMMUNICATIONS - Year 2022
Herein, we report access to phosphinoborinium cations via heterolytic cleavage of the boron-bromide bond in bromophosphinoborane. The product of the reaction was isolated as a dimeric dication possessing a planar P2B2 core. Activation of C-H and C-P bonds in the dication led to formation of the borinium-phosphaborene adduct. Reactivity studies revealed that title cation exhibits ambiphilic properties and intramolecular frustrated...

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