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Abstract
Herein, we report access to phosphinoborinium cations via heterolytic cleavage of the boron-bromide bond in bromophosphinoborane. The product of the reaction was isolated as a dimeric dication possessing a planar P2B2 core. Activation of C-H and C-P bonds in the dication led to formation of the borinium-phosphaborene adduct. Reactivity studies revealed that title cation exhibits ambiphilic properties and intramolecular frustrated Lewis pair features.
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- Copyright (The Royal Society of Chemistry 2022)
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- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
CHEMICAL COMMUNICATIONS
no. 58,
pages 10068 - 10071,
ISSN: 1359-7345 - Language:
- English
- Publication year:
- 2022
- Bibliographic description:
- Kaniewska-Laskowska K., Klimsiak K., Szynkiewicz N., Chojnacki J., Grubba R.: Phosphinoborinium cation: a synthon for cationic B-P bond systems// CHEMICAL COMMUNICATIONS -Vol. 58,iss. 72 (2022), s.10068-10071
- DOI:
- Digital Object Identifier (open in new tab) 10.1039/d2cc02933b
- Sources of funding:
-
- IDUB
- Verified by:
- Gdańsk University of Technology
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