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Abstract
The concept of nonmetallic frustrated cations has been used in small molecule activation. The in situ generated ambiphilic phosphinoborinium cation activated phenyl isocyanate, diisopropylcarbodiimide, and acetonitrile under very mild conditions without any catalyst, yielding single-, double-, or mixed-activation products. Furthermore, the mechanisms of the reactions of the phosphinoborinium cation with small molecules were elucidated using density functional theory calculations.
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Authors (4)
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Marcin Czapla
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- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1039/D3DT01433A
- License
- Copyright (2023 The Royal Society of Chemistry)
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- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
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DALTON TRANSACTIONS
no. 52,
pages 8311 - 8315,
ISSN: 1477-9226 - Language:
- English
- Publication year:
- 2023
- Bibliographic description:
- Kaniewska-Laskowska K., Czapla M., Chojnacki J., Grubba R.: Application of nonmetallic frustrated cations in the activation of small molecules// DALTON TRANSACTIONS -Vol. 52,iss. 24 (2023), s.8311-8315
- DOI:
- Digital Object Identifier (open in new tab) 10.1039/d3dt01433a
- Sources of funding:
-
- IDUB
- Verified by:
- Gdańsk University of Technology
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