Cu supported on various oxides as a candidate catalyst for dry methane reforming in DIR-SOFCs systems - Publication - Bridge of Knowledge

Your account

login

Search

Cu supported on various oxides as a candidate catalyst for dry methane reforming in DIR-SOFCs systems

Abstract

A series of Cu-support systems were tested as potential candidates for DIR-SOFC (Direct Internal Reforming SOFC) catalysts towards a dry reforming of methane (DRM). The various supports (-Al2O3, CeO2, ZrO2, SrTiO3) with comparable specific surface area (SSA), and additionally -Al2O3 with SSA an order of magnitude larger than that of the other supports has been applied. The obtained Cu-support systems were characterized in terms of structure (XRD, XPS), microstructure (SEM), redox properties (TPR /TPOx), and next their catalytic activity and selectivity in DRM reaction were tested. All Cu-support materials show catalytic activity in DRM reaction, but only activity of Cu-SrTiO3 is high (due to the incorporation of Cu into SrTiO3 structure). The catalytic activity of other materials depends on the copper oxidation state (Cu2+ and Cu+). The highest catalytic activity in DRM process was obtained for Cu-AlO(OH) catalyst thanks to an order of greater SSA than in the case of other systems.

Citations

  • 1 1

    CrossRef

  • 0

    Web of Science

  • 1 1

    Scopus

Authors (5)

Cite as

Full text

download paper
downloaded 89 times
Publication version
Accepted or Published Version
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.ijhydene.2022.06.016
License
Creative Commons: CC-BY-NC-ND open in new tab

Keywords

Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY no. 47, pages 25647 - 25661,
ISSN: 0360-3199
Language:
English
Publication year:
2022
Bibliographic description:
Mizera A., Błaszczak P., Bochentyn B., Lach R., Drożdż E.: Cu supported on various oxides as a candidate catalyst for dry methane reforming in DIR-SOFCs systems// INTERNATIONAL JOURNAL OF HYDROGEN ENERGY -Vol. 47,iss. 61 (2022), s.25647-25661
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.ijhydene.2022.06.016
Sources of funding:
  • Free publication
Verified by:
Gdańsk University of Technology

seen 108 times

Recommended for you

Catalytic Activity of Nickel and Ruthenium–Nickel Catalysts Supported on SiO2, ZrO2, Al2O3, and MgAl2O4 in a Dry Reforming Process

2019

Novel sugar-based nickel-tungsten carbide catalysts for dry reforming of hydrocarbons

2023

Nickel phase deposition on V2CTx/V2AlC as catalyst precursors for a dry methane reforming: The effect of the deposition method on the morphology and catalytic activity

2023

Copper and cobalt co-doped ceria as an anode catalyst for DIR-SOFCs fueled by biogas

2019
Meta Tags