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Diiodo-BODIPY Sensitizing of the [Mo3S13]2– Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix
Abstract
We report on a photocatalytic setup that utilizes the organic photosensitizer (PS) diiodo-BODIPY and the non-precious-metal-based hydrogen evolution reaction (HER) catalyst (NH4)2[Mo3S13] together with a polyampholytic unimolecular matrix poly(dehydroalanine)-graft-poly(ethyleneglycol) (PDha-g-PEG) in aqueous media. The system shows exceptionally high performance with turnover numbers (TON > 7300) and turnover frequencies (TOF > 450 h−1) that are typical for noble-metal- containing systems. Excited state absorption spectra reveal the formation of a long-lived triplet state of the PS in both aqueous and organic media. The system is a blueprint for developing noble-metal-free HER in water. Component optimization, e.g., by modification of the meso substituent of the PS and the composition of the HER catalyst, is further possible.
Citations
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9
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0
Web of Science
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9
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Authors (12)
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Daniel Costabel
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Afshin Nabiyan
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Avinash Chettri
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Franz Jacobi
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Magdalena Heiland
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Stephan Kupfer
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Maria WäCHTLER
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Benjamin Dietzek-Ivanšić
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Carsten Streb
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Felix H. Schacher
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Kalina Peneva
Cite as
Full text
- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1021/acsami.2c18529
- License
- Copyright (2023 American Chemical Society)
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
ACS Applied Materials & Interfaces
no. 15,
pages 20833 - 20842,
ISSN: 1944-8244 - Language:
- English
- Publication year:
- 2023
- Bibliographic description:
- Costabel D., Nabiyan A., Chettri A., Jacobi F., Heiland M., Guthmuller J., Kupfer S., Wächtler M., Dietzek-Ivanšić B., Streb C., Schacher F. H., Peneva K.: Diiodo-BODIPY Sensitizing of the [Mo3S13]2– Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix// ACS Applied Materials & Interfaces -Vol. 15,iss. 17 (2023), s.20833-20842
- DOI:
- Digital Object Identifier (open in new tab) 10.1021/acsami.2c18529
- Sources of funding:
-
- Free publication
- Verified by:
- Gdańsk University of Technology
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