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Electrochemical oxidation of sulphamerazine at boron-doped diamond electrodes: Influence of boron concentration
Abstract
The boron-doped diamond (BDD) electrodes with different boron concentrations have been tested as electrode material for sulphamerazine (SRM) oxidation in water solution. An investigation of the electrode morphology and molecular structure was carried out using high resolution scanning electron microscopy (SEM) and Raman spectroscopy. Electrochemical results showed clearly that the kinetics and efficiency of SRM oxidation were dependent on the amount of boron incorporated in a diamond film. The mechanism of SRM oxidation was also analysed by cycle voltammograms and by identyfying oxidative species which take part in the degradation process. Te aging of the material during the operation was also studied.
Authors (10)
-
Aleksandra Fabiańska
- University of Gdansk Environmental Engineering
-
Patrycja Zięba
- University of Gdansk Analytical Chemistry, Faculty of Chemistry
-
Tadeusz Ossowski
- University of Gdansk Analytical Chemistry
-
Stoffel D. Janssens
- Hasselt University Institute for Materials Research
-
Ken Haenen
- Hasselt University Institute for Materials Research
-
E.m. Siedlecka
- University of Gdansk Environmental Engineering
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Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
no. 210,
pages 2040 - 2047,
ISSN: 1862-6300 - Language:
- English
- Publication year:
- 2013
- Bibliographic description:
- Fabiańska A., Bogdanowicz R., Zięba P., Ossowski T., Gnyba M., Ryl J., Zieliński A., Janssens S., Haenen K., Siedlecka E.: Electrochemical oxidation of sulphamerazine at boron-doped diamond electrodes: Influence of boron concentration// PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE. -Vol. 210, nr. 10 (2013), s.2040-2047
- Verified by:
- Gdańsk University of Technology
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