Search
Abstract
Two new transuranium metal boron carbides, NpBC and PuBC, have been synthesized. Rietveld refinements of powder XRD patterns of {Np,Pu} BC confirmed in both cases isotypism with the structure type of UBC. Temperature dependent magnetic susceptibility data reveal antiferromagnetic ordering for PuBC below T-N = 44 K, whereas ferromagnetic ordering was found for NpBC below T-C = 61 K. Heat capacity measurements prove the bulk character of the observed magnetic transition for both compounds. The total energy electronic band structure calculations support formation of the ferromagnetic ground state for NpBC and the antiferromagnetic ground state for PuBC.
Citations
-
3
CrossRef
-
0
Web of Science
-
3
Scopus
Authors (8)
-
A. Shick
- Institute of Physics, Academy of Sciences of the Czech Republic Department of Condensed Matter Theory
-
J.-C. Griveau
- Commiss European Communities, Joint Research Centre Institute for Transuranium Elements ITU
-
E. Colineau
- Commiss European Communities, Joint Research Centre Institute for Transuranium Elements ITU
-
M. Falmbigl
- University of Vienna Institute of Chemical Engineering
-
F. Wastin
- Commiss European Communities, Joint Research Centre Institute for Transuranium Elements ITU
-
P. Rogl
- University of Vienna Institute of Chemical Engineering
Cite as
Full text
download paper
downloaded 31 times
- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1063/1.4913564
- License
-
open in new tab
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach recenzowanych i innych wydawnictwach ciągłych
- Published in:
-
APL Materials
no. 4,
pages 1 - 10,
ISSN: 2166-532X - Language:
- English
- Publication year:
- 2015
- Bibliographic description:
- Klimczuk T., Shick A., Kozub A., Griveau J., Colineau E., Falmbigl M., Wastin F., Rogl P.: Ferro- and antiferro-magnetism in (Np, Pu)BC// APL Materials. -Vol. 4., nr. 3(4) (2015), s.1-10
- DOI:
- Digital Object Identifier (open in new tab) 10.1063/1.4913564
- Verified by:
- Gdańsk University of Technology
seen 112 times
Recommended for you
Superconductivity in the intermetallic compound Zr5Al4
- Z. Sobczak,
- M. Winiarski,
- W. Xie
- + 2 authors
2019
Quasi-one-dimensional exchange interactions and short-range magnetic correlations in CuTeO4
- Z. Hasan,
- E. Zoghlin,
- M. Winiarski
- + 4 authors
2024