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Greener organic solvents in analytical chemistry

Abstract

The paper presents the most recent advances in analytical applications of greener organic solvents. Substitution of problematic solvents with more benign organic ones is much easier than shifting to technique applying alternative solvents, such as ionic liquids or supercritical fluids. In the area of liquid chromatography greener mobile phases, much attention is given to application ethanol or acetone instead of acetonitrile. Solvent-based extractions more often include the application of bio-based organic solvents, such as esters, alcohols or terpenes. All solvents applied in analytical sciences should be carefully assessed before their application.

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Category:
Articles
Type:
publikacja w in. zagranicznym czasopiśmie naukowym (tylko język obcy)
Published in:
Current Opinion in Green and Sustainable Chemistry no. 5, pages 1 - 4,
ISSN: 2452-2236
Language:
English
Publication year:
2017
Bibliographic description:
Tobiszewski M., Namieśnik J.. Greener organic solvents in analytical chemistry. Current Opinion in Green and Sustainable Chemistry, 2017, Vol. 5, , s.1-4
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.cogsc.2017.03.002
Bibliography: test
  1. Gałuszka A, Migaszewski Z, Namie snik J: The 12 principles of green analytical chemistry and the SIGNIFICANCE mnemonic of green analytical practices. Trends Anal. Chem. 2013, 50: 78-84. open in new tab
  2. Clark KD, Nacham O, Purslow JA, Pierson SA, Anderson JL: Magnetic ionic liquids in analytical chemistry: a review. Anal. Chim. Acta 2016, 934:9-21. open in new tab
  3. Ballesteros-Gómez A, Dolores Sicilia M, Rubio S: Supramolec- ular solvents in the extraction of organic compounds. A review. Anal. Chim. Acta 2010, 677:108-130. open in new tab
  4. Espino M, de los Ángeles Fernández M, Gomez FJV, Fernanda Silva M: Natural designer solvents for greening analytical chemistry. Trends Anal. Chem. 2016, 76:126-136. open in new tab
  5. Abrahamsson V, Andersson N, Nilsson B, Turner C: Method development in inverse modeling applied to supercritical fluid extraction of lipids. J. Supercrit. Fluids 2016, 111:14-27. open in new tab
  6. Capello C, Fischer U, Hungerbühler K: What is a green solvent? A comprehensive framework for the environmental assess- ment of solvents. Green Chem. 2007, 9:927-934. open in new tab
  7. Prat D, Hayler J, Wells A: A survey of solvent selection guides. Green Chem. 2014, 16:4546-4551. open in new tab
  8. * . Alder CM, Hayler JD, Henderson RK, Redman AM, Shukla L, Shuster LE, Sneddon HF: Updating and further expanding GSK's solvent sustainability guide. Green Chem. 2016, 18: 3879-3890. open in new tab
  9. The paper provides discussion on the parameters considered during greenness assessment, discusses some of problems with solvents assessment and gives an overview of solvents rarely described elsewhere. open in new tab
  10. Tobiszewski M, Tsakovski S, Simeonov V, Namie snik J, Pena- Pereira F: Solvent selection guide based on chemometrics and multicriteria decision analysis. Green Chem. 2015, 17: 4773-4785. open in new tab
  11. Prat D, Pardigon O, Flemming H-W, Letestu S, Ducandas V, Isnard P, Guntrum E, Senac T, Ruisseau S, Cruciani P, Hosek P: Sanofi's solvent selection guide: a step toward more sus- tainable processes. Org. Process Res. Dev. 2013, 17: 1517-1525. open in new tab
  12. Tobiszewski M: Metrics for green analytical chemistry. Anal. Methods 2016, 8:2993-2999. open in new tab
  13. Byrne FP, Jin S, Paggiola G, Petchey THM, Clark JH, Farmer TJ, Hunt AJ, McElroy CR, Sherwood J: Tools and techniques for solvent selection: green solvent selection guides. Sustain. Chem. Process 2016, 4:47. open in new tab
  14. Provides good introduction to solvent selection guides. States the ne- cessity of these tools utilization and discusses their limitations. open in new tab
  15. Taygerly JP, Miller LM, Yee A, Peterson EA: A convenient guide to help select replacement solvents for dichloromethane in chromatography. Green Chem. 2012, 14:3020-3025. open in new tab
  16. * . Shen Yao, Chen B, van Beek TA: Alternative solvents can make preparative liquid chromatography greener. Green Chem. 2015, 17:4073-4081.
  17. Although this paper describes the application of greener solvents as mobile phases in preparative chromatography, it provides review of important aspects related to their selection and application. open in new tab
  18. Tache F, Udrescu S, Albua F, Micale F, Medvedovici A: Greening pharmaceutical applications of liquid chromatography through using propylene carbonate-ethanol mixtures instead of acetonitrile as organic modifier in the mobile phases. J. Pharm. Biomed. Anal. 2013, 75:230-238. open in new tab
  19. Shaaban H, Górecki T: Current trends in green liquid chro- matography for the analysis of pharmaceutically active compounds in the environmental water compartments. Talanta 2015, 132:739-752. open in new tab
  20. Funari CS, Carneiro RL, Khandagale MM, Cavalheiro AJ, Hilder EF: Acetone as a greener alternative to acetonitrile in liquid chromatographic fingerprinting. J. Sep. Sci. 2015, 38: 1458-1465. open in new tab
  21. Satínský D, Brabcová I, Marou sková A, Chocholou s P, Solich P: Green chromatography separation of analytes of greatly differing properties using a polyethylene glycol stationary phase and a low-toxic water-based mobile phase. Anal. Bio- anal. Chem. 2013, 405:6105-6115. open in new tab
  22. Ordo nez EY, Rodil R, Quintana JB, Cela R: Determination of artificial sweeteners in beverages with green mobile phases and high temperature liquid chromatography-tandem mass spectrometry. Food Chem. 2015, 169:162-168. open in new tab
  23. * . Prache N, Abreu S, Sassiat P, Thiébaut D, Chaminade P: Alternative solvents for improving the greenness of normal phase liquid chromatography of lipid classes. J. Chromatogr. A 2016, 1464:55-63. open in new tab
  24. Describes the problem of finding substitutes for problematic solvents used as mobile phase in normal phase liquid chromatography. open in new tab
  25. Spietelun A, Marcinkowski Ł, de la Guardia M, Namie snik J: Green aspects, developments and perspectives of liquid phase microextraction techniques. Talanta 2014, 119:34-45. open in new tab
  26. Bigus P, Namie snik J, Tobiszewski M: Application of multi- criteria decision analysis in solvent type optimization for chlorophenols determination with a dispersive liquid-liquid microextraction. J. Chromatogr. A 2016, 1446:21-26. open in new tab
  27. Wang L, Littlewood J, Murphy RJ: An economic and environ- mental evaluation for bamboo-derived bioethanol. RSC Adv. 2014, 4:29604-29611. open in new tab
  28. * . Pena-Pereira F, Kloskowski A, Namie snik J: Perspectives on the replacement of harmful organic solvents in analytical meth- odologies: a framework toward the implementation of a generation of eco-friendly alternatives. Green Chem. 2015, 17: 3687-3705. open in new tab
  29. It provides list of bio-based solvents that may gain more attention by analysts in the nearest future. open in new tab
  30. Ahmadkalaei SPJ, Gan S, Ng HK, Talib SA: Investigation of ethyl lactate as a green solvent for desorption of total pe- troleum hydrocarbons (TPH) from contaminated soil. Environ. Sci. Pollut. Res. 2016, 23:22008-22018.
  31. Tenne S-J, Kinzel J, Arlt M, Sibilla F, Bocola M, Schwaneberg U: 2-Methyltetrahydrofuran and cyclopentylmethylether: two green solvents for efficient purification of membrane proteins like FhuA. J. Chromatogr. B 2013, 937:13-17. open in new tab
  32. Sharma K, Mahato N, Hwan Cho M, Rok Lee Y: Converting citrus wastes into value-added products: economic and environmently friendly approaches. Nutrition 2017, 34:29-46. open in new tab
  33. Veillet S, Tomao V, Ruiz K, Chemat F: Green procedure using limonene in the Dean-Stark apparatus for moisture deter- mination in food products. Anal. Chim. Acta 2010, 674:49-52. open in new tab
  34. Virot M, Tomao V, Ginies C, Visinoni F, Chemat F: Green pro- cedure with a green solvent for fats and oils' determination Microwave-integrated Soxhlet using limonene followed by microwave Clevenger distillation. J. Chromatogr. A 2008, 1196-1197:147-152. open in new tab
  35. Medvedovici A, Udrescu S, David V: Use of a green (bio) sol- vent -limonene -as extractant and immiscible diluent for large volume injection in the RPLC-tandem MS assay of statins and related metabolites in human plasma. Biomed. Chromatogr. 2013, 27:48-57. open in new tab
  36. Tobiszewski M, Namie snik J, Pena-Pereira F: Environmental risk -based ranking of solvents by the combination of multimedia model and multi-criteria decision analysis. Green Chem. 2017, 19:1034-1043. open in new tab
  37. Leng Kua Y, Gan S, Morris A, Kiat Ng H: Ethyl lactate as a potential green solvent to extract hydrophilic (polar) and lipophilic (non-polar) phytonutrients simultaneously from fruit and vegetable by-products. Sustain. Chem. Pharm. 2016, 4:21-31. open in new tab
  38. Li Z, Smith KH, Stevens GW: The use of environmentally sustainable bio-derived solvents in solvent extraction appli- cations-a review. Chin. J. Chem. Eng 2016, 24:215-220. open in new tab
  39. Grudpan K, Hartwell SK, Lapanantnoppakhun S, McKelvie I: The case for the use of unrefined natural reagents in analytical chemistry-a green chemical perspective. Anal. Methods 2010, 2:1651-1661. open in new tab
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Gdańsk University of Technology

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