Influence of electropolymerization conditions on the morphological and electrical properties of PEDOT film - Publication - MOST Wiedzy

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Influence of electropolymerization conditions on the morphological and electrical properties of PEDOT film

Abstract

In this work the effects of electropolymerization conditions on the morphological properties and conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) film have been studied. PEDOT films were electrochemically synthesized in a one step process from acetonitrile solution containing 3,4-ethylenedioxythiophene (EDOT) and lithium perchlorate. Based on atomic force microscopy, scanning electron microscopy, cyclic voltammetry and impedance spectroscopy measurements, the morphological properties such as the of structure, double layer capacitance and thus the polymer surface area have been determined. It was shown that depending on the deposition conditions applied, different structures and film surface area could be obtained. Impedance measurements performed during deposition showed different resistance behavior and conductivity. The relationship between structure and conductivity of PEDOT film obtained under different deposition conditions has been discussed.

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Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
ELECTROCHIMICA ACTA no. 176, pages 156 - 161,
ISSN: 0013-4686
Language:
English
Publication year:
2015
Bibliographic description:
Cysewska K., Karczewski J., Jasiński P.: Influence of electropolymerization conditions on the morphological and electrical properties of PEDOT film// ELECTROCHIMICA ACTA. -Vol. 176, (2015), s.156-161
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.electacta.2015.07.006
Verified by:
Gdańsk University of Technology

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