Ion recognition properties of new pyridine-2,6-dicarboxamide bearing propeller-like pendant residues: multi-spectroscopic approach - Publication - Bridge of Knowledge

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Ion recognition properties of new pyridine-2,6-dicarboxamide bearing propeller-like pendant residues: multi-spectroscopic approach

Abstract

The synthesis and ion binding properties of new amide derived from propeller-like tris(2-pyridyl)amine and 2,6-pyridinedicarboxylic acid chloride were described. Amide binds divalent metal cations: copper(II), nickel(II), zinc(II), and lead(II) in acetonitrile. In acetonitrile:water mixture (9:1 v/v) amide interacts only with copper(II) and nickel(II) cations forming complexes of 1:1 stoichiometry. It was found that the introduction of bulky, nitrogen donor atom bearing pendant groups can influence coordination mode of pyridine-2,6-dicarboxamides. The probable model of ligand-ion interactions is proposed on the basis of 1H NMR and FT-IR spectroscopy.

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
MONATSHEFTE FUR CHEMIE no. 151, pages 331 - 343,
ISSN: 0026-9247
Language:
English
Publication year:
2020
Bibliographic description:
Wagner-Wysiecka E., Łukasik N., Okuniewski A., Galiński B.: Ion recognition properties of new pyridine-2,6-dicarboxamide bearing propeller-like pendant residues: multi-spectroscopic approach// MONATSHEFTE FUR CHEMIE -Vol. 151, (2020), s.331-343
DOI:
Digital Object Identifier (open in new tab) 10.1007/s00706-020-02558-w
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