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Reactions of Lithium Salts of Triphosphanes tBu2P-PLi-PtBu2 and tBu2P-PLi-P(NEt2)2 with Metal Complexes [(R3P)2MCl2] (M = Ni, Pd, Pt, R3P = Et3P, pTol3P, Ph2EtP, iPr3P)
Abstract
tBu2P-PLi-PtBu2·2THF reacts with [(R3P)2MCl2] (M = Pt, Pd, Ni; R3P = Et3P, pTol3P, Ph2EtP, iPr3P) to yield isomers of [(1,2-η-tBu2P=P-PtBu2)M(PR3)Cl], in which the tBu2P-P-PtBu2 ligand adopts the arrangement of a side-on bonded 1,1-di-tert-butyl-2-(di-tert-butylphosphanyl)diphosphenium cation. tBu2P-PLi-P(NEt2)2·2THF reacts with [(R3P)2MCl2] but does not form complexes with a tBu2P-P-P(NEt2)2 moiety, however, splitting of a P-P(NEt2)2 bond of the parent triphosphane takes place.
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
no. 636,
ISSN: 0044-2313 - Language:
- English
- Publication year:
- 2010
- Bibliographic description:
- Wiśniewska A., Kazimierczuk K., Grubba R., Matern E., Pikies J.: Reactions of Lithium Salts of Triphosphanes tBu2P-PLi-PtBu2 and tBu2P-PLi-P(NEt2)2 with Metal Complexes [(R3P)2MCl2] (M = Ni, Pd, Pt, R3P = Et3P, pTol3P, Ph2EtP, iPr3P)// ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. -Vol. 636, nr. iss. 8 (2010),
- Verified by:
- Gdańsk University of Technology
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