Abstract
Ionic liquids (ILs) are used in various fields of chemistry. One of them is CO2 capture, a process that is quite well described. The solubility of CO2 in ILs can be used as a model to investigate gas absorption processes. The aim is to find the relationships between the solubility of CO2 and other variables—physicochemical properties and parameters related to greenness. In this study, 12 variables are used to describe a dataset consisting of 26 ILs and 16 molecular solvents. We used a cluster analysis, a principal component analysis, and a K-means hierarchical clustering to find the patterns in the dataset and the discriminators between the clusters of compounds. The results showed that ILs and molecular solvents form two well-separated groups, and the variables were well separated into greenness-related and physicochemical properties. Such patterns suggest that the modeling of greenness properties and of the solubility of CO2 on physicochemical properties can be difficult.
Citations
-
3
CrossRef
-
0
Web of Science
-
2
Scopus
Authors (4)
Cite as
Full text
- Publication version
- Accepted or Published Version
- License
- open in new tab
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
MOLECULES
no. 25,
pages 1 - 13,
ISSN: 1420-3049 - Language:
- English
- Publication year:
- 2020
- Bibliographic description:
- Bystrzanowska M., Tobiszewski M., Pena-Pereira F., Simeonov V.: Searching for Solvents with an Increased Carbon Dioxide Solubility Using Multivariate Statistics// MOLECULES -Vol. 25,iss. 5 (2020), s.1-13
- DOI:
- Digital Object Identifier (open in new tab) 10.3390/molecules25051156
- Bibliography: test
-
- Anastas, P.T.; Warner, J.C. Green Chemistry; Frontiers: Lausanne, Switzerland, 1998; p. 640. open in new tab
- Namieśnik, J. Green analytical chemistry-some remarks. J. Sep. Sci. 2001, 24, 151-153. [CrossRef] open in new tab
- Welch, C.J.; Wu, N.; Biba, M.; Hartman, R.; Brkovic, T.; Gong, X.; Helmy, R.; Schafer, W.; Cuff, J.; Pirzada, Z.; et al. Greening analytical chromatography. Trends Anal. Chem. 2010, 29, 667-680. [CrossRef] open in new tab
- Sheldon, R.A. Green solvents for sustainable organic synthesis: State of the art. Green Chem. 2005, 7, 267-278. [CrossRef] open in new tab
- Koel, M.; Kaljurand, M. Application of the principles of green chemistry in analytical chemistry. Pure Appl. Chem. 2006, 78, 1993-2002. [CrossRef] open in new tab
- Welton, T. Solvents and sustainable chemistry. Proc. R. Soc. A Math. Phys. Eng. Sci. 2015, 471, 20150502. [CrossRef] open in new tab
- Pena-Pereira, F.; Tobiszewski, M. Initial Considerations. In The Application of Green Solvents in Separation Processes; open in new tab
- Pena-Pereira, F., Tobiszewski, M., Eds.; Elsevier: Amsterdam, The Netherlands, 2017; pp. 3-16. [CrossRef] open in new tab
- Chiappe, C.; Pieraccini, D. Ionic liquids: Solvent properties and organic reactivity. J. Phys. Org. Chem. 2005, 18, 275-297. [CrossRef] open in new tab
- Eshetu, G.G.; Armand, M.; Ohno, H.; Scrosati, B.; Passerini, S. Ionic liquids as tailored media for the synthesis and processing of energy conversion materials. Energy Environ. Sci. 2016, 9, 49-61. [CrossRef] open in new tab
- Paiva, A.; Craveiro, R.; Aroso, I.; Martins, M.; Reis, R.L.; Duarte, A.R.C. Natural deep eutectic solvents-solvents for the 21st century. ACS Sustain. Chem. Eng. 2014, 2, 1063-1071. [CrossRef] open in new tab
- Bystrzanowska, M.; Pena-Pereira, F.; Marcinkowski, Ł.; Tobiszewski, M. How green are ionic liquids?-A multicriteria decision analysis approach. Ecotoxicol. Environ. Saf. 2019, 174, 455-458. [CrossRef] open in new tab
- Pham, T.P.T.; Cho, C.W.; Yun, Y.S. Environmental fate and toxicity of ionic liquids: A review. Water Res. 2010, 44, 352-372. [CrossRef] open in new tab
- Coleman, D.; Gathergood, N. Biodegradation studies of ionic liquids. Chem. Soc. Rev. 2010, 39, 600-637. [CrossRef] [PubMed] open in new tab
- Siedlecka, E.M.; Czerwicka, M.; Neumann, J.; Stepnowski, P.; Fernándex, J.F.; Thöming, J. Ionic liquids: Methods of degradation and recovery. In Ionic Liquids: Theory, Properties, New Approaches; InTech: Rijeka, Croatia, 2011; pp. 701-722. open in new tab
- Matzke, M.; Thiele, K.; Müller, A.; Filser, J. Sorption and desorption of imidazolium based ionic liquids in different soil types. Chemosphere 2009, 74, 568-574. [CrossRef] [PubMed] open in new tab
- Stepnowski, P.; Mrozik, W.; Nichthauser, J. Adsorption of alkylimidazolium and alkylpyridinium ionic liquids onto natural soils. Environ. Sci. Technol. 2007, 41, 511-516. [CrossRef] [PubMed] open in new tab
- Stolte, S.; Matzke, M.; Arning, J.; Böschen, A.; Pitner, W.R.; Welz-Biermann, U.; Jastorff, B.; Ranke, J. Effects of different head groups and functionalised side chains on the aquatic toxicity of ionic liquids. Green Chem. 2007, 9, 1170-1179. [CrossRef] open in new tab
- Sild, S.; Piir, G.; Neagu, D.; Maran, U. Storing and using qualitative and quantitative structure-activity relationships in the era of toxicological and chemical data expansion. Big Data Predict. Toxicol. 2019, 185-213. [CrossRef] open in new tab
- EPA Website. Available online: https://www.epa.gov/tsca-screening-tools/epi-suitetm-estimation-program- interface (accessed on 30 January 2020). open in new tab
- Figueroa, J.D.; Fout, T.; Plasynski, S.; McIlvried, H.; Srivastava, R.D. Advances in CO 2 capture technology-the US Department of Energy's Carbon Sequestration Program. Int. J. Greenh. Gas Control 2008, 2, 9-20. [CrossRef] open in new tab
- Keith, D.W. Why capture CO2 from the atmosphere? Science 2009, 325, 1654-1655. [CrossRef] open in new tab
- Sarmad, S.; Mikkola, J.P.; Ji, X. Carbon dioxide capture with ionic liquids and deep eutectic solvents: A new generation of sorbents. ChemSusChem 2017, 10, 324-352. [CrossRef] open in new tab
- Yu, K.M.K.; Curcic, I.; Gabriel, J.; Tsang, S.C.E. Recent advances in CO 2 capture and utilization. ChemSusChem 2008, 1, 893-899. [CrossRef] open in new tab
- Rahman, F.A.; Aziz, M.M.A.; Saidur, R.; Bakar, W.A.W.A.; Hainin, M.R.; Putrajaya, R.; Hassan, N.A. Pollution to solution: Capture and sequestration of carbon dioxide (CO 2 ) and its utilization as a renewable energy source for a sustainable future. Renew. Sustain. Energy Rev. 2017, 71, 112-126. [CrossRef] open in new tab
- Lee, B.S.; Lin, S.T. Screening of ionic liquids for CO 2 capture using the COSMO-SAC model. Chem. Eng. Sci. 2015, 121, 157-168. [CrossRef] open in new tab
- Privalova, E.; Rasi, S.; Mäki-Arvela, P.; Eränen, K.; Rintala, J.; Murzin, D.Y.; Mikkola, J.P. CO 2 capture from biogas: Absorbent selection. RSC Adv. 2013, 3, 2979-2994. [CrossRef] open in new tab
- Zhang, Y.; Ji, X.; Xie, Y.; Lu, X. Screening of conventional ionic liquids for carbon dioxide capture and separation. Appl. Energy 2016, 162, 1160-1170. [CrossRef] open in new tab
- Safarov, J.; Hamidova, R.; Stephan, M.; Kul, I.; Shahverdiyev, A.; Hassel, E. Carbon dioxide solubility in 1-hexyl-3-methylimidazolium bis (trifluormethylsulfonyl)imide in a wide range of temperatures and pressures. J. Phys. Chem. B 2014, 118, 6829-6838. [CrossRef] [PubMed] open in new tab
- Reddy, R.G. Novel applications of ionic liquids in materials processing. In Journal of Physics: Conference Series; IOP Publishing: Bristol, UK, 2009; Volume 165, p. 012076. open in new tab
- Tobiszewski, M.; Namieśnik, J.; Pena-Pereira, F. A derivatisation agent selection guide. Green Chem. 2017, 19, 5911-5922. [CrossRef] open in new tab
- Massart, D.L.; Kaufman, L. The Interpretation of Analytical Chemical Data by the Use of Cluster Analysis;
- Wiley Interscience: New York, NY, USA, 1983.
- Verified by:
- Gdańsk University of Technology
seen 111 times
Recommended for you
How green are ionic liquids? – A multicriteria decision analysis approach
- M. Bystrzanowska,
- P. Francisco,
- Ł. Marcinkowski
- + 1 authors