Search
Synthesis, Structure, and Spectroscopic Properties of Calcium Thiophenecarboxylate Polymers. Structural Comparison with Analogous Lead Complexes
Abstract
Three novel calcium coordination polymers [Ca(2tpCOO)2(2mpa)(H2O)]n (1), [Ca(3tpCOO)2(2mpa)(H2O)]n (2), and {[Ca(3tpacCOO)2(H2O)2]⋅⋅⋅H2O}n (3) (2tpCOO− or 3tpCOO− – thiophene-2- or thiophene-3-carboxylate, 3tpacCOO− – thiophene-3-acetate, 2mpa – 2-methylpropanal), were synthesised using a self-assembly method. The obtained polymers were characterised using SC-XRD, FTIR, UV-Vis DRS, thermogravimetric and luminescence analyses. The polymer fluorescence studies showed that calcium complexes can emit light of different colours ranging from violet (1) and blue (2) to green (3). The molecular structure of each polymer consists of a calcium ion at the centre of a dodecahedral coordination sphere. The crystal structure consists of one dimensional zigzag chains that form a three-dimensional network via π⋅⋅⋅π, C−H⋅⋅⋅π and O−H⋅⋅⋅O or O−H⋅⋅⋅S interactions. Additionally, a comparative structural analysis of CaCPs with lead(II) coordination polymers containing analogous linkers was performed as part of modelling studies to explore the substitution of calcium ions by lead ions in biological polymers.
Citations
-
1
CrossRef
-
0
Web of Science
-
1
Scopus
Authors (5)
-
Joanna Masternak dr hab.
-
Bogumiła Kupcewicz
-
Jakub Brzeski
-
Mateusz Kowalik
Cite as
Full text
full text is not available in portal
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
no. 29,
pages 1 - 10,
ISSN: 1434-1948 - Language:
- English
- Publication year:
- 2022
- Bibliographic description:
- Masternak J., Kazimierczuk K., Kupcewicz B., Brzeski J., Kowalik M.: Synthesis, Structure, and Spectroscopic Properties of Calcium Thiophenecarboxylate Polymers. Structural Comparison with Analogous Lead Complexes// EUROPEAN JOURNAL OF INORGANIC CHEMISTRY -Vol. 29, (2022), s.1-10
- DOI:
- Digital Object Identifier (open in new tab) 10.1002/ejic.202200353
- Sources of funding:
-
- Free publication
- Verified by:
- Gdańsk University of Technology
seen 93 times
Recommended for you
A comparison of structural and luminescence properties of lead(II) coordination polymers with isomeric thiophenecarboxylate ligands
- M. Kowalik,
- J. Masternak,
- K. Kazimierczuk
- + 3 authors
Lead(II) coordination polymers with imidazole-4- and pyrazole-3-carboxylate isomeric linkers: Structural diversity and luminescence properties
- M. Kowalik,
- J. Masternak,
- K. Kazimierczuk
- + 3 authors
Copper and copper-manganese 1D coordination polymers: Synthesis optimization, crystal structure and preliminary studies as catalysts for Baylis–Hillman reactions
- J. C. D. de Andrade,
- L. A. T. Silva,
- C. G. Lima-Junior
- + 5 authors