Tomasz Wojnowski - Publications - Bridge of Knowledge

Tomasz Wojnowski

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Year 2023

Phosphinoborenium cations stabilized by N-heterocyclic carbenes: synthesis, structure, and reactivity
Publication
- K. Kaniewska-Laskowska
- A. Ordyszewska
- T. Wojnowski
- H. Halenka
- M. Czapla
- J. Chojnacki
- R. Grubba
- DALTON TRANSACTIONS - Year 2023
Phosphinoborenium cations stabilized by N-heterocyclic carbenes (NHCs) were synthesized via the reaction of bromo(phosphino)boranes with NHCs. Their structures were investigated by heteronuclear magnetic resonance spectroscopy, X-ray diffraction, and density functional theory calculations. They possess a planar trigonal boron center directly bonded with the pyramidal phosphanyl group (PR2) and can be treated as cationic phosphinoboranes....

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