Rok 2019

• A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties

  Publikacja

  • A. Mielcarek
  • A. Bieńko
  • P. Saramak
  • J. Jezierska
  • A. Dołęga

  - DALTON TRANSACTIONS - Rok 2019

  Mononuclear and polymeric complexes of zinc(II) and copper(II) have been synthesized using two isomers of the hemi-salen ligand with a different mutual orientation of donor atoms. The heterometallic Cu/Zn metallocycle features a catalytic niche filled with the molecule of water and molecules of methanol. This unusual compound exhibits both pronounced catalytic activity in the reaction of oxidation of a secondary alcohol to ketone...

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