Wyniki wyszukiwania dla: ELECTRONIC DEUSITY

• π-Stacking attraction vs. electrostatic repulsion: competing supramolecular interactions in a tpphz-bridged Ru(ii)/Au(iii) complex

  Publikacja

  • D. Sorsche
  • M. Schaub
  • F. Heinemann
  • J. Habermehl
  • S. Kuhri
  • D. Guldi
  • J. Guthmuller
  • S. Rau

  - DALTON TRANSACTIONS - Rok 2016

  The synthesis and characterization of a mixed metal ruthenium(II)/gold(III) complex bridged by tetrapyridophenazine (tpphz) are described. It is isostructural and isoelectronic to the well-known photocatalysts with palladium(II) or platinum(II). Concentration dependent 1H-NMR spectroscopy and XRD studies show that the electrostatic repulsion between the gold(III) moieties exceeds the attractive π-stacking interaction. Theoretical...

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