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• Crystal and electronic structures of Ni(II) silanethiolates containing flexible diamine ligands

  Publikacja

  • A. Pladzyk
  • A. Ożarowski
  • Ł. Ponikiewski

  - INORGANICA CHIMICA ACTA - Rok 2016

  Five nickel(II) complexes containing aliphatic diamines and tri-tert-butoxysilanethiolate ligand have been synthesized for the purpose of studying their structural, spectral (IR, UV–Vis, HF EPR) and thermal properties. Complexes (1)–(5) have been prepared in high yield by reactions of [Ni{SSi(OtBu)3}2(NH3)(H2O)] with 1.3-propanediamine (L1), 1,6-hexanediamine (L2), or 1,7-heptanediamine (L3). The X-ray structures were determined...

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