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• Hunting for the Magnesium(I) Species: Formation, Structure, andReactivity of some Donor-Free Grignard Compounds

  Publikacja

  • T. Kruczyński
  • N. Pushkarevsky
  • P. Henke
  • R. Koppe
  • E. Baum
  • S. Konchenko
  • J. Pikies
  • H. Schnockel

  - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION - Rok 2012

  Magnesium bromide radicals have to be prepared as high-temperature molecules and trapped as a metastable solution because a seemingly simple reduction of donor-free Grignard compounds failed. However, the essential role of magnesium(I) species during the formation of Grignard compounds could be demonstrated experimentally.

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