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• Convenient and Efficient Diastereoselective Preparation of Functionalized Z -Alkenyl Sulfides

  Publikacja

  • J. Doroszuk
  • M. Musiejuk
  • Ł. Ponikiewski
  • D. Witt

  - EUROPEAN JOURNAL OF ORGANIC CHEMISTRY - Rok 2018

  We have developed an efficient and convenient regio‐ and stereoselective reduction of the alkynyl sulfides with pinacolborane in the presence of copper(I) chloride to produce (Z)‐alkenyl sulfides in good and very good yields. The functionalized alkynyl sulfides are readily available based on the reaction of lithium acetylides with thiotosylates under mild conditions.

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