Wyszukiwarka
Wyniki wyszukiwania dla: THIOPHOSPHINOYLATION
Wyświetlane wyniki pochodzą z wyszukiwania alternatywnego.
Filtry
wszystkich: 1
Wyniki wyszukiwania dla: THIOPHOSPHINOYLATION
-
Unexpected Z/E isomerism of N-methyl-O-phosphothioyl benzohydroxamic acids, their oxyphilic reactivity and inertness to amines
PublikacjaThiophosphinoylation of N-methyl p-substituted benzohydroxamic acids using disulfanes (method A) or diphenylphosphinothioyl chloride (method B) provides only one conformer of the respective O-phosphothioyl derivative (Xray and NMR analysis). Undergoing the P-transamidoxylation reaction is an evidence of the reversibility of thiophosphinoylation. Only those products containing strong EWG substituents in the aroyl residue or bulky...