Diethyl carbonate as a green extraction solvent for chlorophenol determination with dispersive liquid–liquid microextraction
Abstract
The principles of green analytical chemistry indicate that the search for greener organic solvents for extraction applications is crucial. In this study diethyl carbonate (DEC) is proved to be a green solvent, as it is relatively nontoxic, obtainable from renewable resources and biodegradable. Here it is applied as an extraction solvent for chlorophenol determination in water samples with dispersive liquid–liquid microextraction. The multiobjective optimization for 7 chlorophenols is done with the design of an experiment combined with Derringer's desirability function. The optimized parameters in the extraction step are 300 mL of DEC, 0.5 mL of methanol, 8 mL of water sample and 7.5% of inorganic salt addition. The values of LOQ are from 0.01 to 0.3 mg L1, and CVs are between 7.1 and 17.3% for 7 CPs. In this study DEC is proved to be a promising, green solvent, applicable in analytical extractions.
Citations
-
2 2
CrossRef
-
0
Web of Science
-
2 2
Scopus
Authors (3)
Cite as
Full text
- Publication version
- Accepted or Published Version
- License
- Copyright (The Royal Society of Chemistry 2019)
Keywords
Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
Analytical Methods
no. 11,
edition 6,
pages 844 - 850,
ISSN: 1759-9660 - Language:
- English
- Publication year:
- 2019
- Bibliographic description:
- Tobiszewski M., Zabrocka W., Bystrzanowska M.: Diethyl carbonate as a green extraction solvent for chlorophenol determination with dispersive liquid–liquid microextraction// Analytical Methods. -Vol. 11, iss. 6 (2019), s.844-850
- DOI:
- Digital Object Identifier (open in new tab) 10.1039/c8ay02683a
- Bibliography: test
-
- S. Armenta, S. Garrigues and M. de la Guardia, TrAC Trends Anal. Chem., 2008, 27(6), 497-511. open in new tab
- A. Spietelun, Ł. Marcinkowski, M. de la Guardia and J. Namieśnik, J. Chromatogr. A, 2013, 1321, 1-13. open in new tab
- L. Kocúrová, I. S. Balogh and V. Andruch, Microchem. J., 2013, 110, 599-607. open in new tab
- C. Capello, U. Fischer and K. Hungerbühler, Green Chem., 2007, 9(9), 927-934. open in new tab
- F. P. Byrne, S. Jin, G. Paggiola, T. H. M. Petchey, J. H. Clark, T. J. Farmer, A. J. Hunt, C. R. McElroy, J. Sherwood, Sustainable Chem. Processes, 2016, 4(1), 1-24. open in new tab
- D. Prat, A. Wells, J. Hayler, H. Sneddon, C. R. McElroy, S. Abou-Shehada and P. J. Dunn, Green Chem., 2015, 18(1), 288-296. open in new tab
- B. Schaffner, F. Schaffner, S. P. Verevkin, A. Borner, Chem.Rev., 2010, 110(8), 4554-4581. open in new tab
- N. S. Roh, B. C. Dunn, E. M. Eyring, R. J. Pugmire and H. L. Meuzelaar, Fuel process. Technol., 2003, 83(1-3), 27-38. open in new tab
- J. Gu, Y. Gao, X. Xu, J. Wu, L. Yu, Z. Xin and S. Sun, Fuel, 2018, 216, 781-786. open in new tab
- D. Li, W. Fang, Y. Xing, Y. Guo and R. Lin, J. hazard. Mater., 2009, 161(2-3), 1193-1201. open in new tab
- F. Mueller, N. Loeffler, G. T. Kim, T. Diemant, R. J. Behm and S. Passerini, ChemSusChem, 2016, 9(11), 1290-1298. open in new tab
- H. Zheng, B. Li, Y. Fu, T. Abe and Z. Ogumi, Electrochim. acta, 2006, 52(4), 1556-1562. open in new tab
- S. Udayakumar, A. Pandurangan and P. K. Sinha, Appl. Catal. A: General, 2005, 287(1), 116-128. open in new tab
- J. Olejniczak, J. Staniewski and J. Szymanowski, Anal. Chim. Acta, 2005, 535(1-2), 251- 257. open in new tab
- P. Viñas, N. Campillo, I. López-García and M. Hernández-Córdoba, Anal. Bioanal. Chem., 2014, 406(8), 2067-2099. open in new tab
- J. Ma, W. Lu and L. Chen, Curr. Anal. Chem., 2012, 8(1), 78-90. open in new tab
- L. Kocúrová, I. S. Balogh, J. Šandrejová and V. Andruch, Microchem. J., 2012, 102, 11-17. open in new tab
- Y. Wu, L. Dai, J. Cheng, F. Guo and J. Li, Chromatographia, 2010, 72(7-8), 695-699. open in new tab
- M. Pera-Titus, V. Garcıá-Molina, M. A. Baños, J. Giménez and S. Esplugas, Appl. Catal. B:, 2004, 47(4), 219-256. open in new tab
- M. Czaplicka, Sci. Total Environ., 2004, 322(1-3), 21-39. open in new tab
- P. Bigus, A. Szalkiewicz, J. Namiesnik and M. Tobiszewski, Curr. Anal. Chem., 2017, 13(3), 262-268. open in new tab
- L. Hou, G. Shen, H. K. Lee, J. Chromatogr. A, 2003, 985(1-2), 107-116. open in new tab
- C. Basheer, H. K. Lee, J. Chromatogr. A, 2004, 1057, 163-169 open in new tab
- H. Bagheri, A. Saber, S. R. Mousavi, J. Chromatogr. A, 2004, 1046, 27-33 open in new tab
- H. Xu, Y. Liao, J. Yao, J. Chromatogr. A, 2007, 1167, 1-8 19 open in new tab
- N. Fattahi, Y. Assadi, M.R.M. Hosseini, E.Z. Jahromi, J. Chromatogr. A, 2007, 1157, 23- 29 open in new tab
- G. Koller, U. Fischer, K. Hungerbühler, Ind. Eng. Chem. Res, 2000, 39(4), 960-972. open in new tab
- Environmental management -Life cycle assessment -Principles and framework, EN ISO 14040, European Committee for Standardisation, Brussels, Belgium, 1997. open in new tab
- I. E. Muskat and F. Strain, US Pat., 2 379 250, 1941.
- K. Shukla and V. C. Srivastava, RSC Adv., 2016, 6(39), 32624-32645. open in new tab
- A. A. G. Shaikh and S. Sivaram, Chem. Rev., 1996, 96(3), 951-976. open in new tab
- D. J. Miller and P. McWilliams, Tenside Surfact. Det., 2010, 47(1), 28-33. open in new tab
- A. Verliefde, N. Van Vliet, G. Amy, B. Van der Bruggen, J. C. Van Dijk, Water Pract. Technol., 2006, 1(4) open in new tab
- G. Bornmann and A. Loeser, Archiv für Toxikologie, 1966, 22(2), 98-114. open in new tab
- D. Brown, I. F. Gaunt, J. Hardy, I. S. Kiss and K. R. Butterworth, Toxicology, 1978, 10, 291-295. open in new tab
- A. K. Das, B. N. Rajasekhar, S. Krishnakumar, J. Quant. Spectrosc. Radiat. Transfer, 2018, 217, 53-62. open in new tab
- R. K. Henderson, C. Jiménez-González, D. J. Constable, S. R. Alston, G. G. Inglis, G. Fisher and A. D. Curzons, Green Chem., 2011, 13(4), 854-862. open in new tab
- C. M. Alder, J. D. Hayler, R. K. Henderson, A. M. Redman, L. Shukla, L. E. Shuster, H. F. open in new tab
- Sneddon, Green Chem., 2016, 18(13), 3879-3890.
- Verified by:
- Gdańsk University of Technology
seen 120 times
Recommended for you
Application of additional factors supporting the microextraction process
- M. Rutkowska,
- K. Owczarek,
- M. d. l. Guardia
- + 2 authors