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Abstract
We have developed a convenient method for the synthesis of functionalized unsymmetrical dialkyl trisulfanes under mild conditions in very good yields. The designed method is based on the reaction of (5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)-disulfanyl derivatives with alkyl disulfanyl anions generated in situ from S-acetyl disulfanyl derivatives and sodium methoxide. The developed method allows for the preparation of unsymmetrical trisulfanes bearing additional hydroxyl, carboxyl, or amino functionalities on both sides of the trisulfane functionality.
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- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1055/s-0033-1338966
- License
- Copyright (2013 Georg Thieme Verlag Stuttgart)
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
SYNLETT
edition 24,
pages 1927 - 1930,
ISSN: 0936-5214 - Language:
- English
- Publication year:
- 2013
- Bibliographic description:
- Lach S., Witt D.: Efficient Synthesis of Functionalized Unsymmetrical Dialkyl Trisulfanes// SYNLETT. -, iss. 24 (2013), s.1927-1930
- Verified by:
- Gdańsk University of Technology
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