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From Donor‐Acceptor Ligands to Smart Coordination Polymers: Cyanothiazole‐Cu(I) Complexes for Multifunctional Electronic Devices
Abstract
Cyanothiazoles possess remarkable optical properties that can be fine-tuned through coordination with transition metals. In this study, we investigate a promising application of cyanothiazoles, where their combination with copper(I) iodide forms a new class of complexes exhibiting outstanding optical properties. X-ray crystallography of copper(I) iodide complexes with isomeric cyanothiazoles revealed key structural features, such as π─π stacking, hydrogen bonding, and rare halogen⋅⋅⋅chalcogen I⋅⋅⋅S interactions, enhancing stability and reactivity. Advanced spectroscopy and computational modeling allowed precise identification of spectral signatures in Fourier-transform infrared (FTIR), nuclear magnetic resonance (NMR), and ultraviolet-visible (UV–Vis) spectra. Fluorescence studies and X-ray absorption near edge structure (XANES) synchrotron analyses highlighted their unique thermal and electronic properties, providing a solid foundation for further research in the field.
Citations
Authors (13)
-
Agnieszka Podborska Dr
-
Tomasz Mazur dr
-
Andrzej Sławek Dr
-
Ramesh Sivasamy
-
Alexey Maximenko
-
Łukasz Orzeł
-
Janusz Oszajca
-
Grażyna Stochel
-
Amarjith V. Dev
-
Chakkooth Vijayakumar
-
Konrad Szaciłowski prof. dr hab.
Cite as
Full text
- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1002/chem.202500215
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Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
CHEMISTRY-A EUROPEAN JOURNAL
ISSN: 0947-6539 - Language:
- English
- Publication year:
- 2025
- Bibliographic description:
- Gutmańska K., Podborska A., Mazur T., Sławek A., Sivasamy R., Maximenko A., Orzeł Ł., Oszajca J., Stochel G., Dev A. V., Vijayakumar C., Szaciłowski K., Dołęga A.: From Donor‐Acceptor Ligands to Smart Coordination Polymers: Cyanothiazole‐Cu(I) Complexes for Multifunctional Electronic Devices// CHEMISTRY-A EUROPEAN JOURNAL -, (2025),
- DOI:
- Digital Object Identifier (open in new tab) 10.1002/chem.202500215
- Sources of funding:
- Verified by:
- Gdańsk University of Technology
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