Rheology of potato starch chemically modified with microwave-assisted reactions - Publication - Bridge of Knowledge

Your account

login

Search

Rheology of potato starch chemically modified with microwave-assisted reactions

Abstract

Native potato starch was sulfated, selenated, borated, silicated and zincatated by means of microwave-assisted reactions with varying doses of relevant reagents. Resulting products were characterized involving rheological behavior of pastes, their weight-average molecular weight (Mw), and radius of gyration (Rg). Most of the pastes showed shear-thinning behavior, with the flow behavior index (n) below unity. The pastes of starch sulfated and borated with boric acid exhibited n higher than native potato starch paste. They had significantly lower consistency index (K) and plastic viscosity and no yield stress. Mw values of these starches were considerably reduced. The pastes of starch selenate, borate after borax, and silicate after silicic acid, with n lower than native potato starch, had similarly lower K and plastic viscosity but, simultaneously, they showed non-zero yield stress values, and yield stress, Mw and Rg of starch selenate were reagent concentration dependent. Also magnitudes of n, K, plastic viscosity, yield stress, Mw and Rg of pastes of starch silicate after sodium metasilicate and zincatate were reagent concentration dependent. While their n rose with concentration, K and plastic viscosity significantly decreased, and yield stress ceased. The effect of temperature on the apparent viscosity of modified starch pastes followed Arrhenius equation.

Citations

  • 1 5

    CrossRef

  • 0

    Web of Science

  • 1 9

    Scopus

Authors (4)

Cite as

Full text

download paper
downloaded 113 times
Publication version
Accepted or Published Version
License
Creative Commons: CC-BY-NC-ND open in new tab

Keywords

Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
LWT-FOOD SCIENCE AND TECHNOLOGY no. 53, edition 1, pages 249 - 254,
ISSN: 0023-6438
Language:
English
Publication year:
2013
Bibliographic description:
Staroszczyk H., Fiedorowicz M., Opalińska-Piskorz J., Tylingo R.: Rheology of potato starch chemically modified with microwave-assisted reactions// LWT-FOOD SCIENCE AND TECHNOLOGY. -Vol. 53, iss. 1 (2013), s.249-254
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.lwt.2013.01.009
Bibliography: test
  1. Aberle, Th., Burchard, W., Vorwerg, W., & Radosta, S. (1994). Conformational con- tribution of amylose and amylopectin to the structural properties of starches from various sources. Starch/Stärke, 46, 329e335. open in new tab
  2. Bello-Perez, L. A., Paredes-Lopez, O., Roger, P., & Colonna, P. (1996). Molecular characteristics of some amylopectins. Cereal Chemistry, 73, 12e17. open in new tab
  3. Bhandari, P. N., Singhal, R. S., & Kale, D. D. (2002). Effect of succinylation on the rheological profile of starch pastes. Carbohydrate Polymers, 47, 365e371. open in new tab
  4. Djakovic, L. J., & Dokic, P. (1972). Rheological characteristics of starch gels. Starch/ Stärke, 24, 195e201. open in new tab
  5. Holdsworth, S. D. (1971). Applicability of rheological models to the interpretation of flow and processing behavior of fluid food products. Journal of Texture Studies, 2, 393e418. open in new tab
  6. Kaur, B., Ariffin, F., Bhat, R., & Karim, A. A. (2012). Progress in starch modification in the last decade. Food Hydrocolloids, 26, 398e404. open in new tab
  7. Lacroix, M. (2009). Mechanical and permeability properties of edible films and coatings for food and pharmaceutical applications. In M. E. Embuscado, & open in new tab
  8. K. C. Huber (Eds.), Edible films and coatings for food applications (pp. 347e366). New York: Springer. open in new tab
  9. Lewandowicz, G., Fornal, J., Walkowski, A., Mą czy nski, M., Urbaniak, G., & Szyma nska, G. (2000). Starch esters obtained by microwave radiationestruc- ture and functionality. Industrial Crops and Products, 11, 249e257. open in new tab
  10. Mao, G.-J., Wang, P., Meng, X.-S., Zhang, X., & Zheng, T. (2006). Crosslinking of corn starch with sodium trimetaphosphate in solid state by microwave irradiation. Journal of Applied Polymer Science, 102, 5854e5860.
  11. Najgebauer, D., Grega, T., Sady, M., & Tomasik, P. (2003). Polymeric complexes from casein and starch phosphate: characteristics and enzyme susceptibility. Journal of Polymer and the Environment, 12, 17e25.
  12. Najgebauer, D., Grega, T., Sady, M., & Tomasik, P. (2004). Polymeric complexes of cornstarch and waxy cornstarch phosphates with milk casein and their per- formance as biodegradable materials. Molecules, 9, 550e567. open in new tab
  13. Rao, M. A. (1999). Flow and functional models for rheological properties of fluid foods. In M. A. Rao (Ed.), Rheology of fluid and semisolid foods (pp. 25e57). Maryland: Aspen Publication. open in new tab
  14. Rutiaga, M. O., Galan, L. J., Morales, L. H., Gordon, S. H., Imam, S. H., Orts, W. J., et al. (2005). Mechanical property and biodegradability of cast films prepared from blends of oppositely charged biopolymers. Journal of Polymers and the Envi- ronment, 13(2), 185e191. open in new tab
  15. Schramm, G. (1994). A practical approach to rheology and rheometry (2nd ed.). Karlsruhe: Gebrueder HAAKE GmbH.
  16. Staroszczyk, H. (2009a). Microwave-assisted boration of potato starch. Polimery, 54, 31e41. open in new tab
  17. Staroszczyk, H. (2009b). Microwave-assisted silication of potato starch. Carbohy- drate Polymers, 77, 506e515. open in new tab
  18. Staroszczyk, H., Fiedorowicz, M., Zhong, W., Janas, P., & Tomasik, P. (2007). Micro- wave assisted solid-state sulphation of starch. e-Polymers, 140. open in new tab
  19. Staroszczyk, H., & Janas, P. (2010b). Microwave-assisted synthesis of zinc derivatives of potato starch. Carbohydrate Polymers, 80, 962e969. open in new tab
  20. Staroszczyk, H., & Janas, P. (2010a). Microwave-assisted preparation of potato starch silicated with silicic acid. Carbohydrate Polymers, 81, 599e606. open in new tab
  21. Staroszczyk, H., Tomasik, P., Janas, P., & Poreda, A. (2007). Esterification of starch with sodium selenite and selenate. Carbohydrate Polymers, 69, 299e304. open in new tab
  22. Tolstoguzov, V. B. (1986). Functional properties of proteinepolysaccharide mixtures. In J. R. Mitchell, & D. A. Ledward (Eds.), Functional properties of food macro- molecules (pp. 385e415). London: Elsevier Applied Science.
  23. Tomasik, P., & Horton, D. (2013). Enzymatic conversions of starch. Avances in Car- bohydrate Chemistry and Biochemistry, 68, 59e436. open in new tab
  24. Tomasik, P., & Schilling, C. H. (1998a). Starch complexes. Part I., complexes with inorganic guests. Advances in Carbohydrate Chemistry and Biochemistry, 53, 263e343. open in new tab
  25. Tomasik, P., & Schilling, C. H. (1998b). Starch complexes. Part II., complexes with organic guests. Advances in Carbohydrate Chemistry and Biochemistry, 53, 345e426. open in new tab
  26. Tomasik, P., & Schilling, C. H. (2004). Chemical modification of starch. Advances in Carbohydrate Chemistry and Biochemistry, 59, 175e403. open in new tab
  27. Tomasik, P., Wiejak, S., & Palasinski, M. (1989). The thermal decomposition of car- bohydrates. Part II. Advances in Carbohydrate Chemistry and Biochemistry, 47, 279e344. open in new tab
  28. Tomasik, P., & Zaranyika, M. F. (1995). Non-conventional modifications of starch. Advances in Carbohydrate Chemistry and Biochemistry, 51, 243e318. open in new tab
  29. Zaleska, H., Ring, S. G., & Tomasik, P. (2000). Apple pectin complexes with whey protein isolate. Food Hydrocolloids, 14, 377e382. open in new tab
  30. Zaleska, H., Ring, S. G., & Tomasik, P. (2001a). Complexes of potato starch with casein. International Journal of Food Science & Technology, 36, 509e515. open in new tab
  31. Zaleska, H., Ring, S., & Tomasik, P. (2001b). Electrosynthesis of potato starchewhey protein isolate complexes. Carbohydrate Polymers, 45, 89e94. open in new tab
Verified by:
Gdańsk University of Technology

seen 129 times

Recommended for you

Microwave-assisted synthesis of zinc derivatives of potato starch

2010

Injectable poloxamer/graphene oxide hydrogels with well‐controlled mechanical and rheological properties

2019

Manufacture and research of TPS/PE biocomposites properties

2015

Functional properties of packaging materials from chemical modified stach.

2010
Meta Tags