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Structure and electrical properties of Y, Fe-based perovskite mixed conducting composites fabricated by a modified polymer precursor method
Abstract
In this work, samples of Y0.07Sr0.93Ti1-xFexO3-d with 20, 40, 60 and 80 mol% of iron amount were prepared by a low-temperature polymer precursor method. The SEM-EDS analysis proved that analyzed Y0.07Sr0.93Ti1-xFexO3-d samples were composites of two Ti- and Fe-rich perovskite samples. This kind of composite consists of two phases in which one has a good ionic and the other electronic conductivity, which makes such a composite a potential mixed ionic and electronic conductors (MIECs) material. The total electrical conductivities of analyzed samples were measured in air atmosphere (cathode conditions in Solid Oxide Fuel Cell). The values changed from ~103 to 101 S cm1 and depended on the ratio between two observed perovskite phases. The 0.12 S cm1 conductivity value at 800 C for sample with the highest amount of Fe-rich perovskite in the structure makes this composite material a candidate for air electrode in electrochemical devices.
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
SOLID STATE SCIENCES
no. 70,
pages 41 - 46,
ISSN: 1293-2558 - Language:
- English
- Publication year:
- 2017
- Bibliographic description:
- Miruszewski T., Gdaniec P., Rosiński W., Karczewski J., Bochentyn B., Kusz B.: Structure and electrical properties of Y, Fe-based perovskite mixed conducting composites fabricated by a modified polymer precursor method// SOLID STATE SCIENCES. -Vol. 70, (2017), s.41-46
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.solidstatesciences.2017.06.008
- Verified by:
- Gdańsk University of Technology
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