Search results for: TERTIARY AMINES
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Convenient and efficient N-methylation of secondary amines under solvent-free ball milling conditions
PublicationIn the present work, we report the development of a rapid, efcient, and solvent-free procedure for the N-methylation of secondary amines under mechanochemical conditions. After optimization of the milling parameters, a vibrational ball mill was used to synthesize 26 tertiary N-methylated amine derivatives in a short time of 20 min (30 Hz frequency) and high yields ranging from 78 to 95%. An exception was compounds having a hydroxyl...
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Polyurethane-based aerogels: Preparation, properties, and applications
PublicationPolyurethane aerogels (PUAs) are interesting materials because of their high porosity, low density, and low thermal conductivity, which result in their application as thermal insulations. PUAs are mainly synthesized using di- and polyisocyanates, diols or polyols, catalysts (tertiary amines and organometallic), and solvents (which are used as reaction medium, purifying of obtained semiproducts). Preparation procedure involves several...
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Efficient Method for the Synthesis of Functionalized Basic Maleimides
PublicationA three-step procedure involving Diels-Alder condensation of maleic anhydride with furane, formation of N-substituted imide upon reaction with appropriate diamine and a final retro Diels-Alder regeneration of the maleic carbon-carbon double bond is proposed for an unequivocal synthesis of N-substituted basic maleimides. The novel method is characterized by mild reaction conditions, easy work-up, high yields and no need for additional...