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Deep Eutectic Solvents: Properties and Applications in CO2 Separation

Abstrakt

Nowadays, many researchers are focused on finding a solution to the problem of global warming. Carbon dioxide is considered to be responsible for the “greenhouse” effect. The largest global emission of industrial CO2 comes from fossil fuel combustion, which makes power plants the perfect point source targets for immediate CO2 emission reductions. A state-of-the-art method for capturing carbon dioxide is chemical absorption using an aqueous solution of alkanolamines, most frequently a 30% wt. solution of monoethanolamine (MEA). Unfortunately, the usage of alkanolamines has a number of drawbacks, such as the corrosive nature of the reaction environment, the loss of the solvent due to its volatility, and a high energy demand at the regeneration step. These problems have driven the search for alternatives to that method, and deep eutectic solvents (DESs) might be a very good substitute. Many types of DESs have thus far been investigated for efficient CO2 capture, and various hydrogen bond donors and acceptors have been used. Deep eutectic solvents that are capable of absorbing carbon dioxide physically and chemically have been reported. Strategies for further CO2 absorption improvement, such as the addition of water, other co-solvents, or metal salts, have been proposed. Within this review, the physical properties of DESs are presented, and their effects on CO2 absorption capacity are discussed in conjunction with the types of HBAs and HBDs and their molar ratios. The practical issues of using DESs for CO2 separation are also described.

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Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuły w czasopismach
Opublikowano w:
MOLECULES nr 28,
ISSN: 1420-3049
Język:
angielski
Rok wydania:
2023
Opis bibliograficzny:
Cichowska-Kopczyńska I., Nowosielski B., Warmińska D.: Deep Eutectic Solvents: Properties and Applications in CO2 Separation// MOLECULES -Vol. 28,iss. 14 (2023), s.5293-
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3390/molecules28145293
Źródła finansowania:
  • Działalność statutowa/subwencja
Weryfikacja:
Politechnika Gdańska

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