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tDissociative electron attachment to PtBr2in the gas phase was studied in the low electron energy rangefrom zero up to 10 eV with an energy resolution of 150 meV. The experiments were carried out using ahemispherical electron monochromator coupled with a quadrupole mass spectrometer and pulse count-ing acquisition system. The only anion observed was Br−. This ion is formed at three resonance electronenergies: 0.4 eV, 1.2 eV and 7 eV. By the measurements of the Br−formation at different sample tem-peratures (in the 350–430 K range) the 0.4 eV resonance was associated with the electron capture byHBr generated in the apparatus at elevated temperatures. In addition, the thermodynamic thresholds fordissociative electron attachment reactions for platinum(II) bromide were calculated and compared withthe experimental results.
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Autorzy (7)
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K. Tanzer
- University of Innsbruck .
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Andrzej Pelc
- Marie Curie-Sklodowska University Institute of Physics, Mass Spectrometry Department
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S .e. Huber
- University of Innsbruck .
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Paul Scheier
- University of Innsbruck Institute for Ion Physics and Applied Physics and Center of Molecular Biosciences Innsbruck
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M. Probst
- University of Innsbruck Institute for Ion Physics and Applied Physics and Center of Molecular Biosciences Innsbruck
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S. Denifl
- University of Innsbruck Institute for Ion Physics and Applied Physics and Center of Molecular Biosciences Innsbruck
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Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuł w czasopiśmie wyróżnionym w JCR
- Opublikowano w:
-
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
nr 365-366,
strony 152 - 156,
ISSN: 1387-3806 - Język:
- angielski
- Rok wydania:
- 2014
- Opis bibliograficzny:
- Tanzer K., Pelc A., Huber S., Śmiałek-Telega M., Scheier P., Probst M., Denifl S.: Low energy electron attachment to platinum(II) bromide (PtBr2)// INTERNATIONAL JOURNAL OF MASS SPECTROMETRY. -Vol. 365-366, (2014), s.152-156
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.ijms.2013.11.016
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 127 razy
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