Rheological characteristics of oligomeric semiproducts gained via chemical degradation of polyurethane foam using crude glycerin in the presence of different catalysts - Publikacja - MOST Wiedzy

Twoje konto

zaloguj

Wyszukiwarka

Rheological characteristics of oligomeric semiproducts gained via chemical degradation of polyurethane foam using crude glycerin in the presence of different catalysts

Abstrakt

Polyurethane (PU) recycling is a topic of growing interest due to the increasing amount of polyurethane waste. The main purpose of polyurethane chemical recycling is to recover the starting polyol. In this study, a method of polyurethane thermochemical recycling, glycerolysis by means of crude glycerin, is proposed. This work presents a comparative study of commercial catalysts used in order to accelerate the decomposition process, namely triethylamine (TEA), potassium acetate (KAc), 1,4-diazabicyclo[2.2.2]octane (DABCO), sodium hydroxide (NaOH), dibutyltin dilaurate (DbDl), and stannous octoate (StOc).The effect of used catalyst on the chemical structure and rheological properties was studied. The type of catalyst does not have significant influence on the chemical structure, but causes different course of reaction: split- and single-phase in applied conditions. Glycerolysates were measured by Brookfield Rheometer. It was found that repolyols can be described by the Herschel–Bulkely mathematical model in the best accuracy. The investigation showed that the rheological behavior of glycerolysates depended on the catalyst used in glycerolysis process

Cytowania

  • 1 2

    CrossRef

  • 0

    Web of Science

  • 1 4

    Scopus

Autorzy (2)

Cytuj jako

Pełna treść

pobierz publikację
pobrano 0 razy
Wersja publikacji
Accepted albo Published Version
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1002/pen.24466
Licencja
Copyright (2016 Society of Plastics Engineers)

Słowa kluczowe

Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
POLYMER ENGINEERING AND SCIENCE nr 57, wydanie 8, strony 891 - 900,
ISSN: 0032-3888
Język:
angielski
Rok wydania:
2017
Opis bibliograficzny:
Jutrzenka Trzebiatowska P., Datta J.: Rheological characteristics of oligomeric semiproducts gained via chemical degradation of polyurethane foam using crude glycerin in the presence of different catalysts// POLYMER ENGINEERING AND SCIENCE. -Vol. 57, iss. 8 (2017), s.891-900
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1002/pen.24466
Weryfikacja:
Politechnika Gdańska

wyświetlono 99 razy

Publikacje, które mogą cię zainteresować

Thermo-Chemical Decomposition Study of Polyurethane Elastomer Through Glycerolysis Route with Using Crude and Refined Glycerine as a Transesterification Agent

2018

Single-phase product obtained via crude glycerine depolymerisation of polyurethane elastomer: structure characterisation and rheological behaviour

2016

Cast polyurethanes obtained from reactive recovered polyol intermediates via crude glycerine decomposition process

2017

The influence of different glycerine purities on chemical recycling process of polyurethane waste and resulting semi‐products

2018
Meta Tagi