Wyniki wyszukiwania dla: DIMERS

• Anticancer Study on IrIII and RhIII Half-Sandwich Complexes with the Bipyridylsulfonamide Ligand

  Publikacja

  • M. Kowalik
  • J. Masternak
  • M. Olszewski
  • N. Maciejewska
  • K. Kazimierczuk
  • J. Sitkowski
  • A. Dąbrowska
  • A. Chylewska
  • M. Makowski

  - INORGANIC CHEMISTRY - Rok 2024

  Two non-platinum compounds, organometallic half-sandwich complexes [(η 5 -Cp)IrCl(L)]PF 6 (1) and [(η 5 -Cp)RhCl(L)]PF 6 (2) were prepared by treating pentamethylcyclopentadienyl chloride dimers of iridium(III) or rhodium(III) with the obtained 4-amino-N-(2,2'-bipyridin-5- yl)benzenesulfonamide ligand (L) and ammonium hexafluorophosphate. The crystal structures of ligand (L) and complexes 1 and 2 were obtained and then analyzed. Coordination...

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• Intermolecular Interactions of Edaravone in Aqueous Solutions of Ethaline and Glyceline Inferred from Experiments and Quantum Chemistry Computations

  Publikacja

  • P. Cysewski
  • T. Jeliński
  • M. Przybyłek

  - MOLECULES - Rok 2023

  Edaravone, acting as a cerebral protective agent, is administered to treat acute brain infarction. Its poor solubility is addressed here by means of optimizing the composition of the aqueous choline chloride (ChCl)-based eutectic solvents prepared with ethylene glycol (EG) or glycerol (GL) in the three different designed solvents compositions. The slurry method was used for spectroscopic solubility determination in temperatures...

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