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Abstract
A series of 16- and 18-membered azo- and azoxythiacrown ethers have been synthesized by reductive macrocyclization of the respective bis(nitrophenoxy)oxaalkanes. The aromatic residues located in the polyether region of the molecule were introduced to macrocyclic skeletons and their affinities toward different groups of metal cations in ion-selective electrodes were described. X-ray structures for one dinitropodand and one azoxybenzothiacrown exhibiting strong π–π and π–H interactions have been found.
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
TETRAHEDRON
no. 69,
edition 49,
pages 1 - 7,
ISSN: 0040-4020 - Language:
- English
- Publication year:
- 2013
- Bibliographic description:
- Kertmen A., Szczygelska-Tao J., Chojnacki J.: Azo and azoxythiacrown ethers: synthesis and properties// TETRAHEDRON. -Vol. 69, iss. 49 (2013), s.1-7
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.tet.2013.09.100
- Verified by:
- Gdańsk University of Technology
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