Chromium-Catalyzed CO2–Epoxide Copolymerization

Joanna Gurnham; Sandro Gambarotta; IIia Korobkov; Lidia Jasińska-Walc; Robbert Duchateau

doi:10.1021/om5005644

Chromium-Catalyzed CO2–Epoxide Copolymerization

Abstract

Iminopyrrole, aminopyrrole, and aminophosphine ligands were complexed with various chromium sources, producing eight complexes that were tested for their catalytic behavior toward epoxide–CO2 copolymerization. As elucidated by MALDI-TOF-MS, copolymerizations afforded polycarbonates and poly(ether-carbonates) exhibiting linear or cyclic topologies.

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Authors (5)

Joanna Gurnham
- University of Ottawa Department of Chemistry
Sandro Gambarotta
- University of Ottawa Department of Chemistry
IIia Korobkov
- University of Ottawa Department of Chemistry
Lidia Jasińska-Walc dr hab. inż.
Robbert Duchateau
- Eindhoven University of Technology Department of Polymer Chemistry

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Category:: Articles
Type:: artykuł w czasopiśmie wyróżnionym w JCR
Published in:: ORGANOMETALLICS no. 33, pages 4401 - 4409,
ISSN: 0276-7333
Language:: English
Publication year:: 2014
Bibliographic description:: Gurnham J., Gambarotta S., Korobkov I., Jasińska-Walc L., Duchateau R.: Chromium-Catalyzed CO2–Epoxide Copolymerization// ORGANOMETALLICS. -Vol. 33, nr. 17 (2014), s.4401-4409
DOI:: Digital Object Identifier (open in new tab) 10.1021/om5005644
Verified by:: Gdańsk University of Technology