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Iron(III)-selective materials based on a catechol-bearing amide for optical sensing

Abstract

The synthesis and ion-binding properties of a new amide L derived from 3,4-dihydroxybenzoic acid are described. Due to the presence of a catechol unit, the compound interacts selectively with iron(III) in organic solvent (dimethyl sulfoxide, DMSO) to produce a color change from pale yellow to green. The incorporation of the ligand L into polymeric matrices or its encapsulation into surfactant-based spheres enables analyte detection in aqueous solutions. The influence of the ligand environment (i.e. organic solvent, polymeric membrane or micelle) on the properties of the sensing materials is analyzed and the sensors are compared.

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DOI:
Digital Object Identifier (open in new tab) 10.1039/C9AN00188C
License
Copyright (2019 The Royal Society of Chemistry)

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Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
ANALYST no. 144, pages 3119 - 3127,
ISSN: 0003-2654
Language:
English
Publication year:
2019
Bibliographic description:
Łukasik N., Wagner-Wysiecka E., Małachowska A.: Iron(III)-selective materials based on a catechol-bearing amide for optical sensing// ANALYST. -Vol. 144, iss. 9 (2019), s.3119-3127
DOI:
Digital Object Identifier (open in new tab) 10.1039/c9an00188c
Sources of funding:
Verified by:
Gdańsk University of Technology

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