Method for the simultaneous determination of monoaromatic and polycyclic aromatic hydrocarbons in industrial effluents using dispersive liquid-liquid microextraction with GC-MS - Publication - Bridge of Knowledge

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Method for the simultaneous determination of monoaromatic and polycyclic aromatic hydrocarbons in industrial effluents using dispersive liquid-liquid microextraction with GC-MS

Abstract

We present a new method for simultaneous determination of 22 monoaromatic and polycyclic aromatic hydrocarbons in postoxidative effluents from the production of petroleum bitumen using dispersive liquid-liquid microextraction coupled to gas chromatography and mass spectrometry. The eight extraction parameters including the type and volume of extraction and disperser solvent, pH, salting out effect, extraction and centrifugation time were optimized. The low detection limit ranging from 0.36 to 28 μg/L, limit of quantitation (1.1-84 μg/L), good reproducibility and wide linear ranges, as well as the recoveries ranging from 71.74 to 114.67% revealed that the new method allows determination of aromatic hydrocarbons at low concentration levels in industrial effluents having a very complex composition. The developed method was applied to the determination of content of mono- and polycyclic aromatic hydrocarbons in samples of raw postoxidative effluents in which 15 compounds were identified at concentrations ranging from 1.21 to 1017.0 μg/L as well as in effluents after chemical treatment.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
JOURNAL OF SEPARATION SCIENCE no. 41, pages 2360 - 2367,
ISSN: 1615-9306
Language:
English
Publication year:
2018
Bibliographic description:
Makoś P., Fernandes A., Boczkaj G.: Method for the simultaneous determination of monoaromatic and polycyclic aromatic hydrocarbons in industrial effluents using dispersive liquid-liquid microextraction with GC-MS// JOURNAL OF SEPARATION SCIENCE. -Vol. 41, nr. 11 (2018), s.2360-2367
DOI:
Digital Object Identifier (open in new tab) 10.1002/jssc.201701464
Verified by:
Gdańsk University of Technology

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