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Novel Diazocrowns with Pyrrole Residue as Lead(II) Colorimetric Probes

Abstract

Novel 18- and 23-membered diazomacrocycles were obtained with satisfactory yields by diazocoupling of aromatic diamines with pyrrole in reactions carried under high dilution conditions. X-ray structure of macrocycle bearing five carbon atoms linkage was determined and described. Compounds were characterized as chromogenic heavy metal ions receptors. Selective color and spectral response for lead(II) was found in acetonitrile and its mixture with water. Complexation properties of newly obtained macrocycles with a hydrocarbon chain were compared with the properties of their oligoether analogs. The influence of the introduction of hydrocarbon residue as a part of macrocycle on the lead(II) binding was discussed. Selective and sensitive colorimetric probe for lead(II) in aqueous acetonitrile with detection limit 56.1 mg/L was proposed.

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DOI:
Digital Object Identifier (open in new tab) 10.3390/ma14237239
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Category:
Articles
Type:
artykuły w czasopismach
Published in:
Materials no. 14,
ISSN: 1996-1944
Language:
English
Publication year:
2021
Bibliographic description:
Galiński B., Luboch E., Chojnacki J., Wagner-Wysiecka E.: Novel Diazocrowns with Pyrrole Residue as Lead(II) Colorimetric Probes// Materials -Vol. 14,iss. 23 (2021), s.7239-
DOI:
Digital Object Identifier (open in new tab) 10.3390/ma14237239
Sources of funding:
  • Statutory activity/subsidy
Verified by:
Gdańsk University of Technology

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