Thermodynamic study of binary mixtures of 2-propanol with ionic liquids, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexylammonium bis(trifluoromethylsulfonyl)imide - Publication - Bridge of Knowledge

Your account

login

Search

Thermodynamic study of binary mixtures of 2-propanol with ionic liquids, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexylammonium bis(trifluoromethylsulfonyl)imide

Abstract

In this work, densities, speeds of sound, refractive indices and viscosities of three binary mixtures containing the ionic liquids 1-hexyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexyl-ammonium bis(trifluoromethylsulfonyl)imide, mixed with 2-propanol at wide temperature and composition ranges at atmospheric pressure have been measured. From these experimental data, the excess molar volume, excess molar compressibility, deviation in refractive index and deviation in viscosity have been calculated. Excess properties have been correlated with the composition data using Redlich-Kister polynomial equation. The effects of temperature, cation and anion of ionic liquid on the physicochemical properties were analysed and discussed in terms of intermolecular interactions occurring in the studied systems. The Prigogine-Flory-Patterson theory was examined for suitability for the correlation of excess molar volumes with compositions.

Citations

  • 5

    CrossRef

  • 0

    Web of Science

  • 5

    Scopus

Authors (2)

Cite as

Full text

full text is not available in portal

Keywords

Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
JOURNAL OF CHEMICAL THERMODYNAMICS no. 171,
ISSN: 0021-9614
Language:
English
Publication year:
2022
Bibliographic description:
Warmińska D., Cichowska-Kopczyńska I.: Thermodynamic study of binary mixtures of 2-propanol with ionic liquids, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexylammonium bis(trifluoromethylsulfonyl)imide// JOURNAL OF CHEMICAL THERMODYNAMICS -Vol. 171, (2022), s.106789-
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.jct.2022.106789
Sources of funding:
  • Free publication
Verified by:
Gdańsk University of Technology

seen 110 times

Recommended for you

Thermodynamic study of binary mixtures of toluene with ionic liquids, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and 1-butylpyridinium bis(trifluoromethylsulfonyl)imide

2020

Density, sound velocity, viscosity, and refractive index of new morpholinium ionic liquids with amino acid-based anions: Effect of temperature, alkyl chain length, and anion

2019

Measurement of activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide using gas–liquid chromatography

2014

Prototype of electrochemical sensor for measurements of volatile organic compounds in gases

2013
Meta Tags